TY - JOUR
T1 - X-ray and57Fe Mössbauer study on a Fe(III) complex of 2-acetyl-1,3-indandione
AU - Ahmedova, Anife
AU - Rusanov, Ventzislav
AU - Hazell, Alan
AU - Wolny, Juliusz A.
AU - Gochev, Georgi
AU - Trautwein, Alfred X.
AU - Mitewa, Mariana
PY - 2006/7/1
Y1 - 2006/7/1
N2 - Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed Mössbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin-spin magnetic relaxation process. Two different approaches for computer processing of the experimental Mössbauer spectra are considered. © 2006 Elsevier B.V. All rights reserved.
AB - Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed Mössbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin-spin magnetic relaxation process. Two different approaches for computer processing of the experimental Mössbauer spectra are considered. © 2006 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.ica.2006.01.011
DO - 10.1016/j.ica.2006.01.011
M3 - Journal articles
SN - 0020-1693
VL - 359
SP - 3123
EP - 3128
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 10
ER -
