Synthesis, structure, and magnetic properties of a 2,2-dipyridyl-2,5-dihydro-imidazole-1-oxyl-(l-)bridged disilver complex [Ag2L2](SbF6)2: A four-membered ring from two AG(I) ions and two imine nitrogen atoms

Frank Hintermaier; Shahram Mihan; Michael Gerdan; Volker Schünemann; Alfred Trautwein; Wolfgang Beck

doi:10.1002/cber.19961290515

Synthesis, structure, and magnetic properties of a 2,2-dipyridyl-2,5-dihydro-imidazole-1-oxyl-(l-)bridged disilver complex [Ag₂L₂](SbF₆)₂: A four-membered ring from two AG(I) ions and two imine nitrogen atoms

Frank Hintermaier^*, Shahram Mihan, Michael Gerdan, Volker Schünemann, Alfred Trautwein, Wolfgang Beck

^*Corresponding author for this work

Institute of Physics

Ludwig-Maximilians-Universität

12 Citations (Scopus)

Abstract

The reaction of 2,5-dihydro-4,5,5-trimethyl-2,2-di-2-pyridyl-imidazole-1-oxyl (L) with AgSbF₆ gives the complex [Ag₂L₂]²⁺ [SbF₆^-]² which was characterized by X-ray diffraction. - The complex (a biradical) forms a four-membered ring with two Ag(I) ions and two imine nitrogen atoms of the imidazolines with a relatively short Ag-Ag distance [2.839(2) Å]. Magnetic measurements indicate that two nitroxide radicals are slightly coupled.

Original language	English
Journal	Chemische Berichte
Volume	129
Issue number	5
Pages (from-to)	571-573
Number of pages	3
ISSN	0009-2940
DOIs	https://doi.org/10.1002/cber.19961290515
Publication status	Published - 01.01.1996

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Hintermaier, F., Mihan, S., Gerdan, M., Schünemann, V., Trautwein, A., & Beck, W. (1996). Synthesis, structure, and magnetic properties of a 2,2-dipyridyl-2,5-dihydro-imidazole-1-oxyl-(l-)bridged disilver complex [Ag₂L₂](SbF₆)₂: A four-membered ring from two AG(I) ions and two imine nitrogen atoms. Chemische Berichte, 129(5), 571-573. https://doi.org/10.1002/cber.19961290515

@article{ba6aa5faf24e4c08a868edc0dd93e5cb,

title = "Synthesis, structure, and magnetic properties of a 2,2-dipyridyl-2,5-dihydro-imidazole-1-oxyl-(l-)bridged disilver complex [Ag2L2](SbF6)2: A four-membered ring from two AG(I) ions and two imine nitrogen atoms",

abstract = "The reaction of 2,5-dihydro-4,5,5-trimethyl-2,2-di-2-pyridyl-imidazole-1-oxyl (L) with AgSbF6 gives the complex [Ag2L2]2+ [SbF6-]2 which was characterized by X-ray diffraction. - The complex (a biradical) forms a four-membered ring with two Ag(I) ions and two imine nitrogen atoms of the imidazolines with a relatively short Ag-Ag distance [2.839(2) {\AA}]. Magnetic measurements indicate that two nitroxide radicals are slightly coupled.",

author = "Frank Hintermaier and Shahram Mihan and Michael Gerdan and Volker Sch{\"u}nemann and Alfred Trautwein and Wolfgang Beck",

year = "1996",

month = jan,

day = "1",

doi = "10.1002/cber.19961290515",

language = "English",

volume = "129",

pages = "571--573",

journal = "Chemische Berichte",

issn = "0009-2940",

publisher = "American Chemical Society",

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Hintermaier, F, Mihan, S, Gerdan, M, Schünemann, V, Trautwein, A & Beck, W 1996, 'Synthesis, structure, and magnetic properties of a 2,2-dipyridyl-2,5-dihydro-imidazole-1-oxyl-(l-)bridged disilver complex [Ag₂L₂](SbF₆)₂: A four-membered ring from two AG(I) ions and two imine nitrogen atoms', Chemische Berichte, vol. 129, no. 5, pp. 571-573. https://doi.org/10.1002/cber.19961290515

Synthesis, structure, and magnetic properties of a 2,2-dipyridyl-2,5-dihydro-imidazole-1-oxyl-(l-)bridged disilver complex [Ag₂L₂](SbF₆)₂: A four-membered ring from two AG(I) ions and two imine nitrogen atoms. / Hintermaier, Frank; Mihan, Shahram; Gerdan, Michael et al.
In: Chemische Berichte, Vol. 129, No. 5, 01.01.1996, p. 571-573.

Research output: Journal Articles › Journal articles › Research › peer-review

TY - JOUR

T1 - Synthesis, structure, and magnetic properties of a 2,2-dipyridyl-2,5-dihydro-imidazole-1-oxyl-(l-)bridged disilver complex [Ag2L2](SbF6)2: A four-membered ring from two AG(I) ions and two imine nitrogen atoms

AU - Hintermaier, Frank

AU - Mihan, Shahram

AU - Gerdan, Michael

AU - Schünemann, Volker

AU - Trautwein, Alfred

AU - Beck, Wolfgang

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The reaction of 2,5-dihydro-4,5,5-trimethyl-2,2-di-2-pyridyl-imidazole-1-oxyl (L) with AgSbF6 gives the complex [Ag2L2]2+ [SbF6-]2 which was characterized by X-ray diffraction. - The complex (a biradical) forms a four-membered ring with two Ag(I) ions and two imine nitrogen atoms of the imidazolines with a relatively short Ag-Ag distance [2.839(2) Å]. Magnetic measurements indicate that two nitroxide radicals are slightly coupled.

AB - The reaction of 2,5-dihydro-4,5,5-trimethyl-2,2-di-2-pyridyl-imidazole-1-oxyl (L) with AgSbF6 gives the complex [Ag2L2]2+ [SbF6-]2 which was characterized by X-ray diffraction. - The complex (a biradical) forms a four-membered ring with two Ag(I) ions and two imine nitrogen atoms of the imidazolines with a relatively short Ag-Ag distance [2.839(2) Å]. Magnetic measurements indicate that two nitroxide radicals are slightly coupled.

UR - https://www.scopus.com/pages/publications/0001304133

U2 - 10.1002/cber.19961290515

DO - 10.1002/cber.19961290515

M3 - Journal articles

AN - SCOPUS:0001304133

SN - 0009-2940

VL - 129

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EP - 573

JO - Chemische Berichte

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IS - 5

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