Synthesis, molecular and electronic structure of complexes [LNaM IVNaL] (M=Ru,Os; H3L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane)

Katsura Mochizuki; Frank Kesting; Thomas Weyhermüller; Karl Wieghardt; Christian Butzlaff; Alfred X. Trautwein

doi:10.1039/C39940000909

Synthesis, molecular and electronic structure of complexes [LNaM ^IVNaL] (M=Ru,Os; H₃L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane)

Katsura Mochizuki, Frank Kesting, Thomas Weyhermüller, Karl Wieghardt^*, Christian Butzlaff, Alfred X. Trautwein

^*Corresponding author for this work

Institute of Physics

Ruhr-University Bochum

10 Citations (Scopus)

Abstract

The trinuclear complexes [LNaM^IVNaL] (M = Ru 1, Os 2) where L represents the hexadentate ligand 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4, 7-triazacyclononane have been synthesized and 1 has been characterized by X-ray crystallography; complex 1 contains an octahedral M^IVS₆ central core and two trigonal-prismatic terminal LNa units with an N ₃S₃ donor set; the electronic structure of the M ^IVS₆ core (M = Ru, Os), has been established as S = 1 by temperature-dependent magnetic susceptibility measurements.

Original language	English
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	7
Pages (from-to)	909-912
Number of pages	4
ISSN	0022-4936
DOIs	https://doi.org/10.1039/C39940000909
Publication status	Published - 01.12.1994

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@article{1ca0686988c74a94812a64a1757d72bb,

title = "Synthesis, molecular and electronic structure of complexes [LNaM IVNaL] (M=Ru,Os; H3L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane)",

abstract = "The trinuclear complexes [LNaMIVNaL] (M = Ru 1, Os 2) where L represents the hexadentate ligand 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4, 7-triazacyclononane have been synthesized and 1 has been characterized by X-ray crystallography; complex 1 contains an octahedral MIVS6 central core and two trigonal-prismatic terminal LNa units with an N 3S3 donor set; the electronic structure of the M IVS6 core (M = Ru, Os), has been established as S = 1 by temperature-dependent magnetic susceptibility measurements.",

author = "Katsura Mochizuki and Frank Kesting and Thomas Weyherm{\"u}ller and Karl Wieghardt and Christian Butzlaff and Trautwein, \{Alfred X.\}",

year = "1994",

month = dec,

day = "1",

doi = "10.1039/C39940000909",

language = "English",

pages = "909--912",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "7",

}

Synthesis, molecular and electronic structure of complexes [LNaM ^IVNaL] (M=Ru,Os; H₃L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane). / Mochizuki, Katsura; Kesting, Frank; Weyhermüller, Thomas et al.
In: Journal of the Chemical Society, Chemical Communications, No. 7, 01.12.1994, p. 909-912.

Research output: Journal Articles › Journal articles › Research › peer-review

TY - JOUR

T1 - Synthesis, molecular and electronic structure of complexes [LNaM IVNaL] (M=Ru,Os; H3L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane)

AU - Mochizuki, Katsura

AU - Kesting, Frank

AU - Weyhermüller, Thomas

AU - Wieghardt, Karl

AU - Butzlaff, Christian

AU - Trautwein, Alfred X.

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The trinuclear complexes [LNaMIVNaL] (M = Ru 1, Os 2) where L represents the hexadentate ligand 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4, 7-triazacyclononane have been synthesized and 1 has been characterized by X-ray crystallography; complex 1 contains an octahedral MIVS6 central core and two trigonal-prismatic terminal LNa units with an N 3S3 donor set; the electronic structure of the M IVS6 core (M = Ru, Os), has been established as S = 1 by temperature-dependent magnetic susceptibility measurements.

AB - The trinuclear complexes [LNaMIVNaL] (M = Ru 1, Os 2) where L represents the hexadentate ligand 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4, 7-triazacyclononane have been synthesized and 1 has been characterized by X-ray crystallography; complex 1 contains an octahedral MIVS6 central core and two trigonal-prismatic terminal LNa units with an N 3S3 donor set; the electronic structure of the M IVS6 core (M = Ru, Os), has been established as S = 1 by temperature-dependent magnetic susceptibility measurements.

UR - https://www.scopus.com/pages/publications/37049083661

U2 - 10.1039/C39940000909

DO - 10.1039/C39940000909

M3 - Journal articles

AN - SCOPUS:37049083661

SN - 0022-4936

SP - 909

EP - 912

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 7

ER -

Synthesis, molecular and electronic structure of complexes [LNaM ^IVNaL] (M=Ru,Os; H₃L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane)

Abstract

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