TY - JOUR
T1 - Synthesis, molecular and electronic structure of complexes [LNaM IVNaL] (M=Ru,Os; H3L = 1,4,7-tris(4-tert-butyl-2- mercaptobenzyl)-1,4,7-triazacyclononane)
AU - Mochizuki, Katsura
AU - Kesting, Frank
AU - Weyhermüller, Thomas
AU - Wieghardt, Karl
AU - Butzlaff, Christian
AU - Trautwein, Alfred X.
PY - 1994/12/1
Y1 - 1994/12/1
N2 - The trinuclear complexes [LNaMIVNaL] (M = Ru 1, Os 2) where L represents the hexadentate ligand 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4, 7-triazacyclononane have been synthesized and 1 has been characterized by X-ray crystallography; complex 1 contains an octahedral MIVS6 central core and two trigonal-prismatic terminal LNa units with an N 3S3 donor set; the electronic structure of the M IVS6 core (M = Ru, Os), has been established as S = 1 by temperature-dependent magnetic susceptibility measurements.
AB - The trinuclear complexes [LNaMIVNaL] (M = Ru 1, Os 2) where L represents the hexadentate ligand 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4, 7-triazacyclononane have been synthesized and 1 has been characterized by X-ray crystallography; complex 1 contains an octahedral MIVS6 central core and two trigonal-prismatic terminal LNa units with an N 3S3 donor set; the electronic structure of the M IVS6 core (M = Ru, Os), has been established as S = 1 by temperature-dependent magnetic susceptibility measurements.
UR - http://www.scopus.com/inward/record.url?scp=37049083661&partnerID=8YFLogxK
U2 - 10.1039/C39940000909
DO - 10.1039/C39940000909
M3 - Journal articles
AN - SCOPUS:37049083661
SN - 0022-4936
SP - 909
EP - 912
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 7
ER -
