Synthesis and redox properties of mixed-valent octanuclear iron defective hexacubanes and a (CaCl)-capped body-centered six-sided iron(III) polyhedron

Raju Prakash; Rolf W. Saalfrank; Harald Maid; Andreas Scheurer; Frank W. Heinemann; Alfred X. Trautwein; Lars H. Böttger

doi:10.1002/anie.200601478

Synthesis and redox properties of mixed-valent octanuclear iron defective hexacubanes and a (CaCl)-capped body-centered six-sided iron(III) polyhedron

Raju Prakash^*, Rolf W. Saalfrank, Harald Maid, Andreas Scheurer, Frank W. Heinemann, Alfred X. Trautwein, Lars H. Böttger

^*Corresponding author for this work

Institute of Physics

University of Erlangen–Nuremberg

24 Citations (Scopus)

Abstract

(Figure Presented) Available in assorted shapes: Three new oligonuclear complexes self-assemble from tBu-N-diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body-centered six-sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.

Original language	English
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	35
Pages (from-to)	5885-5889
Number of pages	5
ISSN	1433-7851
DOIs	https://doi.org/10.1002/anie.200601478
Publication status	Published - 04.09.2006

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 9 Industry, Innovation, and Infrastructure

Access to Document

10.1002/anie.200601478

Cite this

@article{edae7bc52f7941cea7a6a16772cf1a94,

title = "Synthesis and redox properties of mixed-valent octanuclear iron defective hexacubanes and a (CaCl)-capped body-centered six-sided iron(III) polyhedron",

abstract = "(Figure Presented) Available in assorted shapes: Three new oligonuclear complexes self-assemble from tBu-N-diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body-centered six-sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.",

author = "Raju Prakash and Saalfrank, \{Rolf W.\} and Harald Maid and Andreas Scheurer and Heinemann, \{Frank W.\} and Trautwein, \{Alfred X.\} and B{\"o}ttger, \{Lars H.\}",

year = "2006",

month = sep,

day = "4",

doi = "10.1002/anie.200601478",

language = "English",

volume = "45",

pages = "5885--5889",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

number = "35",

}

Synthesis and redox properties of mixed-valent octanuclear iron defective hexacubanes and a (CaCl)-capped body-centered six-sided iron(III) polyhedron. / Prakash, Raju; Saalfrank, Rolf W.; Maid, Harald et al.
In: Angewandte Chemie - International Edition, Vol. 45, No. 35, 04.09.2006, p. 5885-5889.

Research output: Journal Articles › Journal articles › Research › peer-review

TY - JOUR

T1 - Synthesis and redox properties of mixed-valent octanuclear iron defective hexacubanes and a (CaCl)-capped body-centered six-sided iron(III) polyhedron

AU - Prakash, Raju

AU - Saalfrank, Rolf W.

AU - Maid, Harald

AU - Scheurer, Andreas

AU - Heinemann, Frank W.

AU - Trautwein, Alfred X.

AU - Böttger, Lars H.

PY - 2006/9/4

Y1 - 2006/9/4

N2 - (Figure Presented) Available in assorted shapes: Three new oligonuclear complexes self-assemble from tBu-N-diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body-centered six-sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.

AB - (Figure Presented) Available in assorted shapes: Three new oligonuclear complexes self-assemble from tBu-N-diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body-centered six-sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.

UR - https://www.scopus.com/pages/publications/33748534533

U2 - 10.1002/anie.200601478

DO - 10.1002/anie.200601478

M3 - Journal articles

AN - SCOPUS:33748534533

SN - 1433-7851

VL - 45

SP - 5885

EP - 5889

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 35

ER -

Synthesis and redox properties of mixed-valent octanuclear iron defective hexacubanes and a (CaCl)-capped body-centered six-sided iron(III) polyhedron

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this