TY - JOUR
T1 - Synthesis and redox properties of mixed-valent octanuclear iron defective hexacubanes and a (CaCl)-capped body-centered six-sided iron(III) polyhedron
AU - Prakash, Raju
AU - Saalfrank, Rolf W.
AU - Maid, Harald
AU - Scheurer, Andreas
AU - Heinemann, Frank W.
AU - Trautwein, Alfred X.
AU - Böttger, Lars H.
PY - 2006/9/4
Y1 - 2006/9/4
N2 - (Figure Presented) Available in assorted shapes: Three new oligonuclear complexes self-assemble from tBu-N-diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body-centered six-sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.
AB - (Figure Presented) Available in assorted shapes: Three new oligonuclear complexes self-assemble from tBu-N-diethanolamine and mixtures of iron(II) and iron(III) ions. Depending on the reaction conditions, a compact or linear defective hexacubane, or a body-centered six-sided iron(III) polyhedron (see structure; Fe gold, Ca purple, C gray, N blue, O red, Cl green) is formed.
UR - http://www.scopus.com/inward/record.url?scp=33748534533&partnerID=8YFLogxK
U2 - 10.1002/anie.200601478
DO - 10.1002/anie.200601478
M3 - Journal articles
AN - SCOPUS:33748534533
SN - 1433-7851
VL - 45
SP - 5885
EP - 5889
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 35
ER -
