Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis

I. P. Suzdalev; V. N. Buravtsev; V. K. Imshennik; Yu V. Maksimov; V. V. Matveev; A. V. Volynskaya; A. X. Trautnein; H. Winkler

doi:10.1007/BF01426632

Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis

I. P. Suzdalev^*, V. N. Buravtsev, V. K. Imshennik, Yu V. Maksimov, V. V. Matveev, A. V. Volynskaya, A. X. Trautnein, H. Winkler

^*Corresponding author for this work

Institute of Physics

Russian Academy of Sciences

12 Citations (Scopus)

Abstract

The atomic dynamics of ultrafine clusters of γ-ferric oxide with diameters of 1-3 nm, obtained by thermal decomposition of ferric oxalate, has been studied by gamma-resonance (Mossbauer) spectroscopy and by thermodynamic analysis. The intracluster atomic mobility has been shown to increase by the action of surfactants. Thermodynamical and phenomenological cluster models describing the dynamic state of clusters have been developed and are compared with the experimental data. The conditions for formation of a specific solid-liquid state of clusters are discussed.

Original language	English
Journal	Zeitschrift fur Physik D-Atoms Molecules and Clusters
Volume	36
Issue number	2
Pages (from-to)	163-169
Number of pages	7
ISSN	0178-7683
DOIs	https://doi.org/10.1007/BF01426632
Publication status	Published - 01.06.1996

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10.1007/BF01426632

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Suzdalev, I. P., Buravtsev, V. N., Imshennik, V. K., Maksimov, Y. V., Matveev, V. V., Volynskaya, A. V., Trautnein, A. X., & Winkler, H. (1996). Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis. Zeitschrift fur Physik D-Atoms Molecules and Clusters, 36(2), 163-169. https://doi.org/10.1007/BF01426632

@article{101b63fb2a5641fb801ec4561a49a699,

title = "Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis",

abstract = "The atomic dynamics of ultrafine clusters of γ-ferric oxide with diameters of 1-3 nm, obtained by thermal decomposition of ferric oxalate, has been studied by gamma-resonance (Mossbauer) spectroscopy and by thermodynamic analysis. The intracluster atomic mobility has been shown to increase by the action of surfactants. Thermodynamical and phenomenological cluster models describing the dynamic state of clusters have been developed and are compared with the experimental data. The conditions for formation of a specific solid-liquid state of clusters are discussed.",

author = "Suzdalev, {I. P.} and Buravtsev, {V. N.} and Imshennik, {V. K.} and Maksimov, {Yu V.} and Matveev, {V. V.} and Volynskaya, {A. V.} and Trautnein, {A. X.} and H. Winkler",

year = "1996",

month = jun,

day = "1",

doi = "10.1007/BF01426632",

language = "English",

volume = "36",

pages = "163--169",

journal = "Zeitschrift fur Physik D-Atoms Molecules and Clusters",

issn = "0178-7683",

number = "2",

}

Suzdalev, IP, Buravtsev, VN, Imshennik, VK, Maksimov, YV, Matveev, VV, Volynskaya, AV, Trautnein, AX & Winkler, H 1996, 'Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis', Zeitschrift fur Physik D-Atoms Molecules and Clusters, vol. 36, no. 2, pp. 163-169. https://doi.org/10.1007/BF01426632

Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis. / Suzdalev, I. P.; Buravtsev, V. N.; Imshennik, V. K. et al.
In: Zeitschrift fur Physik D-Atoms Molecules and Clusters, Vol. 36, No. 2, 01.06.1996, p. 163-169.

Research output: Journal Articles › Journal articles › Research › peer-review

TY - JOUR

T1 - Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis

AU - Suzdalev, I. P.

AU - Buravtsev, V. N.

AU - Imshennik, V. K.

AU - Maksimov, Yu V.

AU - Matveev, V. V.

AU - Volynskaya, A. V.

AU - Trautnein, A. X.

AU - Winkler, H.

PY - 1996/6/1

Y1 - 1996/6/1

N2 - The atomic dynamics of ultrafine clusters of γ-ferric oxide with diameters of 1-3 nm, obtained by thermal decomposition of ferric oxalate, has been studied by gamma-resonance (Mossbauer) spectroscopy and by thermodynamic analysis. The intracluster atomic mobility has been shown to increase by the action of surfactants. Thermodynamical and phenomenological cluster models describing the dynamic state of clusters have been developed and are compared with the experimental data. The conditions for formation of a specific solid-liquid state of clusters are discussed.

AB - The atomic dynamics of ultrafine clusters of γ-ferric oxide with diameters of 1-3 nm, obtained by thermal decomposition of ferric oxalate, has been studied by gamma-resonance (Mossbauer) spectroscopy and by thermodynamic analysis. The intracluster atomic mobility has been shown to increase by the action of surfactants. Thermodynamical and phenomenological cluster models describing the dynamic state of clusters have been developed and are compared with the experimental data. The conditions for formation of a specific solid-liquid state of clusters are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0000652041&partnerID=8YFLogxK

U2 - 10.1007/BF01426632

DO - 10.1007/BF01426632

M3 - Journal articles

AN - SCOPUS:0000652041

SN - 0178-7683

VL - 36

SP - 163

EP - 169

JO - Zeitschrift fur Physik D-Atoms Molecules and Clusters

JF - Zeitschrift fur Physik D-Atoms Molecules and Clusters

IS - 2

ER -

Study of intracluster atomic mobility in ultrafine clusters of γ-ferric oxide by Mossbauer spectroscopy and thermodynamical analysis

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