Ruthenium carbene mediated [2+2+2] cyclotrimerizations

Álvaro Mallagaray; Sandra Medina; Gema Domínguez; Javier Pérez-Castells

doi:10.1055/s-0030-1258521

Ruthenium carbene mediated [2+2+2] cyclotrimerizations

Álvaro Mallagaray, Sandra Medina, Gema Domínguez, Javier Pérez-Castells^*

^*Corresponding author for this work

Institute of Chemistry and Metabolomics

Universidad San Pablo CEU

20 Citations (Scopus)

Abstract

Second-generation Grubbs catalyst and Hoveyda-Grubbs catalyst are able to catalyze both crossed [2+2+2] cyclotrimerization of diynes with alkynes and di- or trimerizations of diynes. Selection of the reaction conditions allows us to favor one particular process. The process is selective when applied to unsymmetric diynes.

Original language	English
Article number	G13410ST
Journal	Synlett
Issue number	14
Pages (from-to)	2114-2118
Number of pages	5
ISSN	0936-5214
DOIs	https://doi.org/10.1055/s-0030-1258521
Publication status	Published - 2010

Research Areas and Centers

Academic Focus: Center for Infection and Inflammation Research (ZIEL)

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1055/s-0030-1258521

Cite this

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abstract = "Second-generation Grubbs catalyst and Hoveyda-Grubbs catalyst are able to catalyze both crossed [2+2+2] cyclotrimerization of diynes with alkynes and di- or trimerizations of diynes. Selection of the reaction conditions allows us to favor one particular process. The process is selective when applied to unsymmetric diynes.",

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AU - Domínguez, Gema

AU - Pérez-Castells, Javier

PY - 2010

Y1 - 2010

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AB - Second-generation Grubbs catalyst and Hoveyda-Grubbs catalyst are able to catalyze both crossed [2+2+2] cyclotrimerization of diynes with alkynes and di- or trimerizations of diynes. Selection of the reaction conditions allows us to favor one particular process. The process is selective when applied to unsymmetric diynes.

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U2 - 10.1055/s-0030-1258521

DO - 10.1055/s-0030-1258521

M3 - Journal articles

AN - SCOPUS:77956016265

SN - 0936-5214

SP - 2114

EP - 2118

JO - Synlett

JF - Synlett

IS - 14

M1 - G13410ST

ER -

Ruthenium carbene mediated [2+2+2] cyclotrimerizations

Abstract

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UN SDGs

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