Relaxation as seen by nuclei: Comparison between conventional Mössbauer spectra and nuclear resonant scattering of synchrotron radiation

H. Winkler; W. Meyer-Klaucke; S. Schwendy; A. X. Trautwein; B. F. Matzanke; O. Leupold; H. D. Rüter; M. Haas; E. Realo; D. Mandon; R. Weiss

doi:10.1023/A:1012629212211

Relaxation as seen by nuclei: Comparison between conventional Mössbauer spectra and nuclear resonant scattering of synchrotron radiation

H. Winkler^*, W. Meyer-Klaucke, S. Schwendy, A. X. Trautwein, B. F. Matzanke, O. Leupold, H. D. Rüter, M. Haas, E. Realo, D. Mandon, R. Weiss

^*Corresponding author for this work

Institute of Physics

3 Citations (Scopus)

Abstract

The mechanism of spin-lattice relaxation has been investigated in the "picket-fence" porphyrin [Fe(CH₃COO)(TP_pivP)]^-, a high-spin iron(II) complex with unusual large quadrupole splitting of 4.25 mm s^-1, by conventional Mössbauer spectroscopy as well as by nuclear resonant forward scattering (NFS). Superparamagnetism with a blocking temperature of about 8 K is observable by both methods in the spectra of bacterioferritin from S. olivaceus. From these two examples general conclusions about the merits of both methods can be drawn.

Original language	English
Journal	Hyperfine Interactions
Volume	113
Issue number	1-4
Pages (from-to)	443-448
Number of pages	6
ISSN	0304-3843
DOIs	https://doi.org/10.1023/A:1012629212211
Publication status	Published - 01.12.1998

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 9 Industry, Innovation, and Infrastructure

Access to Document

10.1023/A:1012629212211

Cite this

Winkler, H., Meyer-Klaucke, W., Schwendy, S., Trautwein, A. X., Matzanke, B. F., Leupold, O., Rüter, H. D., Haas, M., Realo, E., Mandon, D., & Weiss, R. (1998). Relaxation as seen by nuclei: Comparison between conventional Mössbauer spectra and nuclear resonant scattering of synchrotron radiation. Hyperfine Interactions, 113(1-4), 443-448. https://doi.org/10.1023/A:1012629212211

@article{d6b5c7d478544fceab957ed087a56488,

title = "Relaxation as seen by nuclei: Comparison between conventional M{\"o}ssbauer spectra and nuclear resonant scattering of synchrotron radiation",

abstract = "The mechanism of spin-lattice relaxation has been investigated in the {"}picket-fence{"} porphyrin [Fe(CH3COO)(TPpivP)]-, a high-spin iron(II) complex with unusual large quadrupole splitting of 4.25 mm s-1, by conventional M{\"o}ssbauer spectroscopy as well as by nuclear resonant forward scattering (NFS). Superparamagnetism with a blocking temperature of about 8 K is observable by both methods in the spectra of bacterioferritin from S. olivaceus. From these two examples general conclusions about the merits of both methods can be drawn.",

author = "H. Winkler and W. Meyer-Klaucke and S. Schwendy and Trautwein, \{A. X.\} and Matzanke, \{B. F.\} and O. Leupold and R{\"u}ter, \{H. D.\} and M. Haas and E. Realo and D. Mandon and R. Weiss",

year = "1998",

month = dec,

day = "1",

doi = "10.1023/A:1012629212211",

language = "English",

volume = "113",

pages = "443--448",

journal = "Hyperfine Interactions",

issn = "0304-3843",

publisher = "Springer Nature",

number = "1-4",

}

Winkler, H, Meyer-Klaucke, W, Schwendy, S, Trautwein, AX, Matzanke, BF, Leupold, O, Rüter, HD, Haas, M, Realo, E, Mandon, D & Weiss, R 1998, 'Relaxation as seen by nuclei: Comparison between conventional Mössbauer spectra and nuclear resonant scattering of synchrotron radiation', Hyperfine Interactions, vol. 113, no. 1-4, pp. 443-448. https://doi.org/10.1023/A:1012629212211

TY - JOUR

T1 - Relaxation as seen by nuclei: Comparison between conventional Mössbauer spectra and nuclear resonant scattering of synchrotron radiation

AU - Winkler, H.

AU - Meyer-Klaucke, W.

AU - Schwendy, S.

AU - Trautwein, A. X.

AU - Matzanke, B. F.

AU - Leupold, O.

AU - Rüter, H. D.

AU - Haas, M.

AU - Realo, E.

AU - Mandon, D.

AU - Weiss, R.

PY - 1998/12/1

Y1 - 1998/12/1

N2 - The mechanism of spin-lattice relaxation has been investigated in the "picket-fence" porphyrin [Fe(CH3COO)(TPpivP)]-, a high-spin iron(II) complex with unusual large quadrupole splitting of 4.25 mm s-1, by conventional Mössbauer spectroscopy as well as by nuclear resonant forward scattering (NFS). Superparamagnetism with a blocking temperature of about 8 K is observable by both methods in the spectra of bacterioferritin from S. olivaceus. From these two examples general conclusions about the merits of both methods can be drawn.

AB - The mechanism of spin-lattice relaxation has been investigated in the "picket-fence" porphyrin [Fe(CH3COO)(TPpivP)]-, a high-spin iron(II) complex with unusual large quadrupole splitting of 4.25 mm s-1, by conventional Mössbauer spectroscopy as well as by nuclear resonant forward scattering (NFS). Superparamagnetism with a blocking temperature of about 8 K is observable by both methods in the spectra of bacterioferritin from S. olivaceus. From these two examples general conclusions about the merits of both methods can be drawn.

UR - https://www.scopus.com/pages/publications/2342472757

U2 - 10.1023/A:1012629212211

DO - 10.1023/A:1012629212211

M3 - Scientific review articles

AN - SCOPUS:2342472757

SN - 0304-3843

VL - 113

SP - 443

EP - 448

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1-4

ER -

Relaxation as seen by nuclei: Comparison between conventional Mössbauer spectra and nuclear resonant scattering of synchrotron radiation

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this