Oxoiron Porphyrin Species with High‐Valent Iron: Formation by Solvent‐Dependent Protonation of a Peroxoiron(III) Porphyrinate Derivative

Dominique Mandon; Raymond Weiss; Michaela Franke; Eckard Bill; Alfred X. Trautwein

doi:10.1002/anie.198917091

Oxoiron Porphyrin Species with High‐Valent Iron: Formation by Solvent‐Dependent Protonation of a Peroxoiron(III) Porphyrinate Derivative

Dominique Mandon, Raymond Weiss^*, Michaela Franke, Eckard Bill, Alfred X. Trautwein

^*Corresponding author for this work

Institute of Physics

Nouvel Hôpital Civil

24 Citations (Scopus)

Abstract

Activation of O₂ by cytochrome P‐450 monooxygenase is generally thought to proceed by way of a peroxoiron(III) porphyrinate species that is then transformed into an oxoiron(IV) porphyrinate radical cation. Such a radical cation, the “picket fence” model compound 1, has now been isolated for the first time from the peroxoiron(III) species by treatment with HBF₄ · Et₂O. (Figure Presented.)

Original language	English
Journal	Angewandte Chemie International Edition in English
Volume	28
Issue number	12
Pages (from-to)	1709-1711
Number of pages	3
ISSN	0570-0833
DOIs	https://doi.org/10.1002/anie.198917091
Publication status	Published - 01.12.1989

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10.1002/anie.198917091

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title = "Oxoiron Porphyrin Species with High‐Valent Iron: Formation by Solvent‐Dependent Protonation of a Peroxoiron(III) Porphyrinate Derivative",

abstract = "Activation of O2 by cytochrome P‐450 monooxygenase is generally thought to proceed by way of a peroxoiron(III) porphyrinate species that is then transformed into an oxoiron(IV) porphyrinate radical cation. Such a radical cation, the “picket fence” model compound 1, has now been isolated for the first time from the peroxoiron(III) species by treatment with HBF4 · Et2O. (Figure Presented.)",

author = "Dominique Mandon and Raymond Weiss and Michaela Franke and Eckard Bill and Trautwein, \{Alfred X.\}",

year = "1989",

month = dec,

day = "1",

doi = "10.1002/anie.198917091",

language = "English",

volume = "28",

pages = "1709--1711",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

number = "12",

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Oxoiron Porphyrin Species with High‐Valent Iron: Formation by Solvent‐Dependent Protonation of a Peroxoiron(III) Porphyrinate Derivative. / Mandon, Dominique; Weiss, Raymond; Franke, Michaela et al.
In: Angewandte Chemie International Edition in English, Vol. 28, No. 12, 01.12.1989, p. 1709-1711.

Research output: Journal Articles › Journal articles › Research › peer-review

TY - JOUR

T1 - Oxoiron Porphyrin Species with High‐Valent Iron: Formation by Solvent‐Dependent Protonation of a Peroxoiron(III) Porphyrinate Derivative

AU - Mandon, Dominique

AU - Weiss, Raymond

AU - Franke, Michaela

AU - Bill, Eckard

AU - Trautwein, Alfred X.

PY - 1989/12/1

Y1 - 1989/12/1

N2 - Activation of O2 by cytochrome P‐450 monooxygenase is generally thought to proceed by way of a peroxoiron(III) porphyrinate species that is then transformed into an oxoiron(IV) porphyrinate radical cation. Such a radical cation, the “picket fence” model compound 1, has now been isolated for the first time from the peroxoiron(III) species by treatment with HBF4 · Et2O. (Figure Presented.)

AB - Activation of O2 by cytochrome P‐450 monooxygenase is generally thought to proceed by way of a peroxoiron(III) porphyrinate species that is then transformed into an oxoiron(IV) porphyrinate radical cation. Such a radical cation, the “picket fence” model compound 1, has now been isolated for the first time from the peroxoiron(III) species by treatment with HBF4 · Et2O. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/0024802841

U2 - 10.1002/anie.198917091

DO - 10.1002/anie.198917091

M3 - Journal articles

AN - SCOPUS:0024802841

SN - 0570-0833

VL - 28

SP - 1709

EP - 1711

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 12

ER -

Oxoiron Porphyrin Species with High‐Valent Iron: Formation by Solvent‐Dependent Protonation of a Peroxoiron(III) Porphyrinate Derivative

Abstract

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