TY - JOUR
T1 - Oxoiron Porphyrin Species with High‐Valent Iron: Formation by Solvent‐Dependent Protonation of a Peroxoiron(III) Porphyrinate Derivative
AU - Mandon, Dominique
AU - Weiss, Raymond
AU - Franke, Michaela
AU - Bill, Eckard
AU - Trautwein, Alfred X.
PY - 1989/12/1
Y1 - 1989/12/1
N2 - Activation of O2 by cytochrome P‐450 monooxygenase is generally thought to proceed by way of a peroxoiron(III) porphyrinate species that is then transformed into an oxoiron(IV) porphyrinate radical cation. Such a radical cation, the “picket fence” model compound 1, has now been isolated for the first time from the peroxoiron(III) species by treatment with HBF4 · Et2O. (Figure Presented.)
AB - Activation of O2 by cytochrome P‐450 monooxygenase is generally thought to proceed by way of a peroxoiron(III) porphyrinate species that is then transformed into an oxoiron(IV) porphyrinate radical cation. Such a radical cation, the “picket fence” model compound 1, has now been isolated for the first time from the peroxoiron(III) species by treatment with HBF4 · Et2O. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=0024802841&partnerID=8YFLogxK
U2 - 10.1002/anie.198917091
DO - 10.1002/anie.198917091
M3 - Journal articles
AN - SCOPUS:0024802841
SN - 0570-0833
VL - 28
SP - 1709
EP - 1711
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -
