Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties

Philippe Ochsenbein; Dominique Mandon; Jean Fischer; Raymond Weiss; Rachel Austin; Karupiah Jayaraj; Avram Gold; James Terner; Eckhard Bill; Markus Müther; Alfred X. Trautwein

doi:10.1002/anie.199314371

Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties

Philippe Ochsenbein, Dominique Mandon, Jean Fischer, Raymond Weiss^*, Rachel Austin, Karupiah Jayaraj, Avram Gold, James Terner, Eckhard Bill, Markus Müther, Alfred X. Trautwein

^*Corresponding author for this work

Institute of Physics

54 Citations (Scopus)

Abstract

Despite significantly different molecular structures and redox potentials, the electronic properties of the oxoferryl cation radical of 1 (M  Fe^IV O instead of M  Fe^IIICl, obtained by oxidation of 1 with m‐chloroperoxyben zoic acid), which shows saddle‐shaped distortions as a result of its peripheral chloro substituents, are similar to those of the corresponding cation radical of the unsubstituted “planar” porphyrin. These results help in the understanding of the different chemoand regioselectivities of halogenated and halogen‐free iron porphyries in the catalytic hydroxylation of alkanes. R  2,4,6 Me₃C₆H₂.

Original language	English
Journal	Angewandte Chemie International Edition in English
Volume	32
Issue number	10
Pages (from-to)	1437-1439
Number of pages	3
ISSN	0570-0833
DOIs	https://doi.org/10.1002/anie.199314371
Publication status	Published - 01.01.1993

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 9 Industry, Innovation, and Infrastructure

Access to Document

10.1002/anie.199314371

Cite this

Ochsenbein, P., Mandon, D., Fischer, J., Weiss, R., Austin, R., Jayaraj, K., Gold, A., Terner, J., Bill, E., Müther, M., & Trautwein, A. X. (1993). Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties. Angewandte Chemie International Edition in English, 32(10), 1437-1439. https://doi.org/10.1002/anie.199314371

@article{bc3f861309dd43cb8248efaebaf7029d,

title = "Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties",

abstract = "Despite significantly different molecular structures and redox potentials, the electronic properties of the oxoferryl cation radical of 1 (M  FeIV O instead of M  FeIIICl, obtained by oxidation of 1 with m‐chloroperoxyben zoic acid), which shows saddle‐shaped distortions as a result of its peripheral chloro substituents, are similar to those of the corresponding cation radical of the unsubstituted “planar” porphyrin. These results help in the understanding of the different chemoand regioselectivities of halogenated and halogen‐free iron porphyries in the catalytic hydroxylation of alkanes. R  2,4,6 Me3C6H2. ",

author = "Philippe Ochsenbein and Dominique Mandon and Jean Fischer and Raymond Weiss and Rachel Austin and Karupiah Jayaraj and Avram Gold and James Terner and Eckhard Bill and Markus M{\"u}ther and Trautwein, \{Alfred X.\}",

year = "1993",

month = jan,

day = "1",

doi = "10.1002/anie.199314371",

language = "English",

volume = "32",

pages = "1437--1439",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

number = "10",

}

Ochsenbein, P, Mandon, D, Fischer, J, Weiss, R, Austin, R, Jayaraj, K, Gold, A, Terner, J, Bill, E, Müther, M & Trautwein, AX 1993, 'Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties', Angewandte Chemie International Edition in English, vol. 32, no. 10, pp. 1437-1439. https://doi.org/10.1002/anie.199314371

Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties. / Ochsenbein, Philippe; Mandon, Dominique; Fischer, Jean et al.
In: Angewandte Chemie International Edition in English, Vol. 32, No. 10, 01.01.1993, p. 1437-1439.

Research output: Journal Articles › Journal articles › Research › peer-review

TY - JOUR

T1 - Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties

AU - Ochsenbein, Philippe

AU - Mandon, Dominique

AU - Fischer, Jean

AU - Weiss, Raymond

AU - Austin, Rachel

AU - Jayaraj, Karupiah

AU - Gold, Avram

AU - Terner, James

AU - Bill, Eckhard

AU - Müther, Markus

AU - Trautwein, Alfred X.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Despite significantly different molecular structures and redox potentials, the electronic properties of the oxoferryl cation radical of 1 (M  FeIV O instead of M  FeIIICl, obtained by oxidation of 1 with m‐chloroperoxyben zoic acid), which shows saddle‐shaped distortions as a result of its peripheral chloro substituents, are similar to those of the corresponding cation radical of the unsubstituted “planar” porphyrin. These results help in the understanding of the different chemoand regioselectivities of halogenated and halogen‐free iron porphyries in the catalytic hydroxylation of alkanes. R  2,4,6 Me3C6H2.

AB - Despite significantly different molecular structures and redox potentials, the electronic properties of the oxoferryl cation radical of 1 (M  FeIV O instead of M  FeIIICl, obtained by oxidation of 1 with m‐chloroperoxyben zoic acid), which shows saddle‐shaped distortions as a result of its peripheral chloro substituents, are similar to those of the corresponding cation radical of the unsubstituted “planar” porphyrin. These results help in the understanding of the different chemoand regioselectivities of halogenated and halogen‐free iron porphyries in the catalytic hydroxylation of alkanes. R  2,4,6 Me3C6H2.

UR - https://www.scopus.com/pages/publications/33748240459

U2 - 10.1002/anie.199314371

DO - 10.1002/anie.199314371

M3 - Journal articles

AN - SCOPUS:33748240459

SN - 0570-0833

VL - 32

SP - 1437

EP - 1439

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 10

ER -

Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this