TY - JOUR
T1 - Oxoferryl π‐Cation Radical of β‐Pyrrole Octachlorinated meso‐Tetramesitylporphyrin: Electronic and Structural Properties
AU - Ochsenbein, Philippe
AU - Mandon, Dominique
AU - Fischer, Jean
AU - Weiss, Raymond
AU - Austin, Rachel
AU - Jayaraj, Karupiah
AU - Gold, Avram
AU - Terner, James
AU - Bill, Eckhard
AU - Müther, Markus
AU - Trautwein, Alfred X.
PY - 1993/1/1
Y1 - 1993/1/1
N2 - Despite significantly different molecular structures and redox potentials, the electronic properties of the oxoferryl cation radical of 1 (M FeIV O instead of M FeIIICl, obtained by oxidation of 1 with m‐chloroperoxyben
zoic acid), which shows saddle‐shaped distortions as a result of its
peripheral chloro substituents, are similar to those of the
corresponding cation radical of the unsubstituted “planar” porphyrin.
These results help in the understanding of the different chemoand
regioselectivities of halogenated and halogen‐free iron porphyries in
the catalytic hydroxylation of alkanes. R 2,4,6 Me3C6H2.
AB - Despite significantly different molecular structures and redox potentials, the electronic properties of the oxoferryl cation radical of 1 (M FeIV O instead of M FeIIICl, obtained by oxidation of 1 with m‐chloroperoxyben
zoic acid), which shows saddle‐shaped distortions as a result of its
peripheral chloro substituents, are similar to those of the
corresponding cation radical of the unsubstituted “planar” porphyrin.
These results help in the understanding of the different chemoand
regioselectivities of halogenated and halogen‐free iron porphyries in
the catalytic hydroxylation of alkanes. R 2,4,6 Me3C6H2.
UR - http://www.scopus.com/inward/record.url?scp=33748240459&partnerID=8YFLogxK
U2 - 10.1002/anie.199314371
DO - 10.1002/anie.199314371
M3 - Journal articles
AN - SCOPUS:33748240459
SN - 0570-0833
VL - 32
SP - 1437
EP - 1439
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 10
ER -