Abstract
Recombination of carbonmonoxide after photodissociation has been studied by Mössbauer spectroscopy at 4.2 K and in the low temperature region, where tunneling effects play an important role in rebinding. We interpret the kinetic results in terms of a radiationless nonadiabatic multiphonon transition, which leads to a uniform description for all temperatures. Prolonged illumination at low temperature results in pumping into long-living states.
| Original language | English |
|---|---|
| Journal | Hyperfine Interactions |
| Volume | 71 |
| Issue number | 1-4 |
| Pages (from-to) | 1291-1294 |
| Number of pages | 4 |
| ISSN | 0304-3843 |
| DOIs | |
| Publication status | Published - 01.04.1992 |
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