Molecular tunneling and pumping effects in low temperature MBCO recombination

M. Franke*, H. Winkler, A. X. Trautwein, F. Parak

*Corresponding author for this work
1 Citation (Scopus)

Abstract

Recombination of carbonmonoxide after photodissociation has been studied by Mössbauer spectroscopy at 4.2 K and in the low temperature region, where tunneling effects play an important role in rebinding. We interpret the kinetic results in terms of a radiationless nonadiabatic multiphonon transition, which leads to a uniform description for all temperatures. Prolonged illumination at low temperature results in pumping into long-living states.

Original languageEnglish
JournalHyperfine Interactions
Volume71
Issue number1-4
Pages (from-to)1291-1294
Number of pages4
ISSN0304-3843
DOIs
Publication statusPublished - 01.04.1992

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