TY - JOUR
T1 - Molecular magnetism of a linear Fe(III)-Mn(II)-Fe(III) complex. Influence of long-range exchange interaction
AU - Lengen, M.
AU - Bill, E.
AU - Butzlaff, C.
AU - Trautwein, A. X.
AU - Winter, M.
AU - Chaudhuri, P.
PY - 1994/12/1
Y1 - 1994/12/1
N2 - The magnetic properties of [L-Fe(III)-dmg3Mn(II)-Fe(III)-L] (ClO4)2 have been characterized by magnetic susceptibility, EPR, and Mössbauer studies. L represents 1,4,7-trimethyl-, 1,4,7-triazacyclononane and dmg represents dimethylglyoxime. X-ray diffraction measurements yield that the arrangement of the three metal centers is strictly linear with atomic distances dFe-Mn=0.35 nm and dFe-Fe=0.7 nm. Magnetic susceptibility measurements (3-295 K) were analyzed in the framework of the spin-Hamiltonian formalism considering Heisenberg exchange and Zeeman interaction:Ĥ=JFe-Mn(SFe1+SFe2)SMn +JFe-Fe(SFe1SFe2) +gΜBStotalB. The spins SFe1=SFe2 =SMn=5/2 of the complex are antiferromagnetically coupled, yielding a total spin of Stotal=5/2 with exchange coupling constants FFe-Mn=13.4 cm-1 and JFe-Fe= 4.5 cm-1. Magnetically split Mössbauer spectra were recorded at 1.5 K under various applied fields (20 m T, 170 mT, 4T). The spin-Hamiltonian analysis of these spectra yields isotropic magnetic hyperfine coupling with Atotal/(gNΜN)=-18.5 T. The corresponding local component AFe is related to Atotal via spin-projection:Atotal=(6/7)AFe. The resulting AFe/(gNΜN)=-21.6 T is in agreement with standard values of ferric high-spin complexes. Spin-Hamiltonian parameters as obtained from Mössbauer studies and exchange coupling constants as derived from susceptibility measurements are corroborated by temperature-dependent EPR studies.
AB - The magnetic properties of [L-Fe(III)-dmg3Mn(II)-Fe(III)-L] (ClO4)2 have been characterized by magnetic susceptibility, EPR, and Mössbauer studies. L represents 1,4,7-trimethyl-, 1,4,7-triazacyclononane and dmg represents dimethylglyoxime. X-ray diffraction measurements yield that the arrangement of the three metal centers is strictly linear with atomic distances dFe-Mn=0.35 nm and dFe-Fe=0.7 nm. Magnetic susceptibility measurements (3-295 K) were analyzed in the framework of the spin-Hamiltonian formalism considering Heisenberg exchange and Zeeman interaction:Ĥ=JFe-Mn(SFe1+SFe2)SMn +JFe-Fe(SFe1SFe2) +gΜBStotalB. The spins SFe1=SFe2 =SMn=5/2 of the complex are antiferromagnetically coupled, yielding a total spin of Stotal=5/2 with exchange coupling constants FFe-Mn=13.4 cm-1 and JFe-Fe= 4.5 cm-1. Magnetically split Mössbauer spectra were recorded at 1.5 K under various applied fields (20 m T, 170 mT, 4T). The spin-Hamiltonian analysis of these spectra yields isotropic magnetic hyperfine coupling with Atotal/(gNΜN)=-18.5 T. The corresponding local component AFe is related to Atotal via spin-projection:Atotal=(6/7)AFe. The resulting AFe/(gNΜN)=-21.6 T is in agreement with standard values of ferric high-spin complexes. Spin-Hamiltonian parameters as obtained from Mössbauer studies and exchange coupling constants as derived from susceptibility measurements are corroborated by temperature-dependent EPR studies.
UR - http://www.scopus.com/inward/record.url?scp=0141893308&partnerID=8YFLogxK
U2 - 10.1007/BF02063706
DO - 10.1007/BF02063706
M3 - Journal articles
AN - SCOPUS:0141893308
SN - 0304-3834
VL - 94
SP - 1849
EP - 1853
JO - Hyperfine Interactions
JF - Hyperfine Interactions
IS - 1
ER -