TY - JOUR
T1 - Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations
AU - Saalfrank, Rolf W.
AU - Burak, Roman
AU - Breit, Alexandra
AU - Stalke, Dietmar
AU - Herbst‐Irmer, Regine
AU - Daub, Jörg
AU - Porsch, Michael
AU - Bill, Eckhard
AU - Müther, Markus
AU - Trautwein, Alfred X.
PY - 1994/9/2
Y1 - 1994/9/2
N2 - In a simple one‐pot reaction the host‐guest compounds 1 (white spheres FeIII; black = FeII; gray = NH 4+; angled rods = 2: R = Me, Et) are accessible in gram quantities by self‐assembly. They are the only fully characterized redox isomers whose cyclic voltammograms display four quasi‐reversible waves and whose mixed‐valent character has been established by Mössbauer spectra. The endohedral complexation of one NH 4+ ion in 1 has been confirmed by X‐ray crystallography. (Figure Presented.)
AB - In a simple one‐pot reaction the host‐guest compounds 1 (white spheres FeIII; black = FeII; gray = NH 4+; angled rods = 2: R = Me, Et) are accessible in gram quantities by self‐assembly. They are the only fully characterized redox isomers whose cyclic voltammograms display four quasi‐reversible waves and whose mixed‐valent character has been established by Mössbauer spectra. The endohedral complexation of one NH 4+ ion in 1 has been confirmed by X‐ray crystallography. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748240270&partnerID=8YFLogxK
U2 - 10.1002/anie.199416211
DO - 10.1002/anie.199416211
M3 - Journal articles
AN - SCOPUS:33748240270
SN - 0570-0833
VL - 33
SP - 1621
EP - 1623
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 15-16
ER -
