TY - JOUR
T1 - Metallocorroles with Formally Tetravalent Iron
AU - Vogel, Emanuel
AU - Will, Stefan
AU - Tilling, Andreas Schulze
AU - Neumann, Ludger
AU - Lex, Johann
AU - Bill, Eckhard
AU - Trautwein, Alfred X.
AU - Wieghardt, Karl
PY - 1994/4/18
Y1 - 1994/4/18
N2 - The unusual oxidation state + IV for iron centers can be stabilized by porphyrin‐like corrole ligands in such a way that the compounds 1 (R Cl, Ph, OFe‐corrole) can be isolated at room temperature. The oxygen‐bridged binuclear iron(IV) corrole, which can be readily converted into the mononuclear iron(IV) corrole, forms as the only defined product from the reaction of the ligand with [Fe2(CO)9] followed by workup in air. In contrast, only a few iron(IV) porphyrins are known so far, and these are too unstable to be isolated as solids. (Figure Presented.)
AB - The unusual oxidation state + IV for iron centers can be stabilized by porphyrin‐like corrole ligands in such a way that the compounds 1 (R Cl, Ph, OFe‐corrole) can be isolated at room temperature. The oxygen‐bridged binuclear iron(IV) corrole, which can be readily converted into the mononuclear iron(IV) corrole, forms as the only defined product from the reaction of the ligand with [Fe2(CO)9] followed by workup in air. In contrast, only a few iron(IV) porphyrins are known so far, and these are too unstable to be isolated as solids. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748216344&partnerID=8YFLogxK
U2 - 10.1002/anie.199407311
DO - 10.1002/anie.199407311
M3 - Journal articles
AN - SCOPUS:33748216344
SN - 0570-0833
VL - 33
SP - 731
EP - 735
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 7
ER -
