METAL-METAL INTERACTIONS IN COMPLEXES WITH A DOUBLE DIMETHYLSILANDIYL-BRIDGED DICYCLOPENTADIENYL LIGAND

U. Siemeling; P. Jutzi; E. Bill; A. X. Trautwein

METAL-METAL INTERACTIONS IN COMPLEXES WITH A DOUBLE DIMETHYLSILANDIYL-BRIDGED DICYCLOPENTADIENYL LIGAND

U. Siemeling, P. Jutzi, E. Bill, A. X. Trautwein

Institute of Physics

Abstract

The metal-metal interaction in the mixed-valence ferrocenium salt [trans-CpFeLFeCp]+PF6- ([5(+)]PF6-) (Cp* = C(5)Me(5), L = C(5)H(3)SiMe(2)) was investigated by cyclic voltammetry, electron spectroscopy, EPR and temperature dependent Mossbauer spectroscopy. The compound is best described as a valence-localised system (class I according to Robin and Day).

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	463
Issue number	1-2
Pages (from-to)	151-154
Number of pages	4
Publication status	Published - 1993

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title = "METAL-METAL INTERACTIONS IN COMPLEXES WITH A DOUBLE DIMETHYLSILANDIYL-BRIDGED DICYCLOPENTADIENYL LIGAND",

abstract = "The metal-metal interaction in the mixed-valence ferrocenium salt [trans-CpFeLFeCp]+PF6- ([5(+)]PF6-) (Cp* = C(5)Me(5), L = C(5)H(3)SiMe(2)) was investigated by cyclic voltammetry, electron spectroscopy, EPR and temperature dependent Mossbauer spectroscopy. The compound is best described as a valence-localised system (class I according to Robin and Day). ",

author = "U. Siemeling and P. Jutzi and E. Bill and Trautwein, \{A. X.\}",

year = "1993",

language = "English",

volume = "463",

pages = "151--154",

journal = "Journal of Organometallic Chemistry",

number = "1-2",

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T1 - METAL-METAL INTERACTIONS IN COMPLEXES WITH A DOUBLE DIMETHYLSILANDIYL-BRIDGED DICYCLOPENTADIENYL LIGAND

AU - Siemeling, U.

AU - Jutzi, P.

AU - Bill, E.

AU - Trautwein, A. X.

PY - 1993

Y1 - 1993

N2 - The metal-metal interaction in the mixed-valence ferrocenium salt [trans-CpFeLFeCp]+PF6- ([5(+)]PF6-) (Cp* = C(5)Me(5), L = C(5)H(3)SiMe(2)) was investigated by cyclic voltammetry, electron spectroscopy, EPR and temperature dependent Mossbauer spectroscopy. The compound is best described as a valence-localised system (class I according to Robin and Day).

AB - The metal-metal interaction in the mixed-valence ferrocenium salt [trans-CpFeLFeCp]+PF6- ([5(+)]PF6-) (Cp* = C(5)Me(5), L = C(5)H(3)SiMe(2)) was investigated by cyclic voltammetry, electron spectroscopy, EPR and temperature dependent Mossbauer spectroscopy. The compound is best described as a valence-localised system (class I according to Robin and Day).

UR - https://pub.uni-bielefeld.de/record/1644739

M3 - Journal articles

VL - 463

SP - 151

EP - 154

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

METAL-METAL INTERACTIONS IN COMPLEXES WITH A DOUBLE DIMETHYLSILANDIYL-BRIDGED DICYCLOPENTADIENYL LIGAND

Abstract

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