The metal-metal interaction in the mixed-valence ferrocenium salt [trans-CpFeLFeCp]+PF6- ([5(+)]PF6-) (Cp* = C(5)Me(5), L = C(5)H(3)SiMe(2)) was investigated by cyclic voltammetry, electron spectroscopy, EPR and temperature dependent Mossbauer spectroscopy. The compound is best described as a valence-localised system (class I according to Robin and Day).
|Journal||Journal of Organometallic Chemistry|
|Number of pages||4|
|Publication status||Published - 1993|