Abstract
From Mössbauer spectra of LiNbO3:57Fe(III) single crystals under external fields of 4.92 and 6.2 T, the crystal field and hyperfine parameters are determined. Transmission integral fits indicate a Boltzmann population of the Fe(III) electronic levels with a spin temperature equal to the sample temperature. Spectra at external fields of 0 T and 19 mT can be satisfactorily simulated using an effective spin 1/2, g-factors calculated from spin-expectation values and an internal averaged dipole field of 5.5 mT inclined 20‡ to the c-axis. The simulations indicate cross-relaxation between Nb and Li nuclear spins and the Fe(III) electronic spin.
Original language | English |
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Journal | Hyperfine Interactions |
Volume | 94 |
Issue number | 1 |
Pages (from-to) | 2005-2010 |
Number of pages | 6 |
ISSN | 0304-3834 |
DOIs | |
Publication status | Published - 01.12.1994 |