Mössbauer studies of coordination compounds using synchrotron radiation

Hauke Paulsen; Volker Schünemann; Alfred X. Trautwein; Heiner Winkler

doi:10.1016/j.ccr.2004.03.005

Mössbauer studies of coordination compounds using synchrotron radiation

Hauke Paulsen, Volker Schünemann, Alfred X. Trautwein^*, Heiner Winkler

^*Corresponding author for this work

Institute of Physics

41 Citations (Scopus)

Abstract

Nuclear resonant forward scattering (NFS) and nuclear inelastic scattering (NIS) of synchrotron radiation are fairly recent spectroscopic methods for the investigation of complexes containing Mössbauer-active transition metal ions. NFS, which can be regarded as Mössbauer spectroscopy in the time domain, overcomes some limitations of conventional Mössbauer spectroscopy as has been demonstrated especially for bioinorganic compounds. NIS extends the energy range of conventional Mössbauer spectroscopy to the range of molecular vibrations. Since NIS is sensitive only to the mean-square displacement of Mössbauer nuclei it can be used as site-selective vibrational spectroscopy. It complements usefully comparable techniques such as IR or Raman spectroscopy. Examples are given for applications to spin crossover complexes, nitroprusside compounds, heme model complexes and myoglobin.

Original language	English
Journal	Coordination Chemistry Reviews
Volume	249
Issue number	1-2
Pages (from-to)	255-272
Number of pages	18
ISSN	0010-8545
DOIs	https://doi.org/10.1016/j.ccr.2004.03.005
Publication status	Published - 01.01.2005

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title = "M{\"o}ssbauer studies of coordination compounds using synchrotron radiation",

abstract = "Nuclear resonant forward scattering (NFS) and nuclear inelastic scattering (NIS) of synchrotron radiation are fairly recent spectroscopic methods for the investigation of complexes containing M{\"o}ssbauer-active transition metal ions. NFS, which can be regarded as M{\"o}ssbauer spectroscopy in the time domain, overcomes some limitations of conventional M{\"o}ssbauer spectroscopy as has been demonstrated especially for bioinorganic compounds. NIS extends the energy range of conventional M{\"o}ssbauer spectroscopy to the range of molecular vibrations. Since NIS is sensitive only to the mean-square displacement of M{\"o}ssbauer nuclei it can be used as site-selective vibrational spectroscopy. It complements usefully comparable techniques such as IR or Raman spectroscopy. Examples are given for applications to spin crossover complexes, nitroprusside compounds, heme model complexes and myoglobin.",

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T1 - Mössbauer studies of coordination compounds using synchrotron radiation

AU - Paulsen, Hauke

AU - Schünemann, Volker

AU - Trautwein, Alfred X.

AU - Winkler, Heiner

PY - 2005/1/1

Y1 - 2005/1/1

N2 - Nuclear resonant forward scattering (NFS) and nuclear inelastic scattering (NIS) of synchrotron radiation are fairly recent spectroscopic methods for the investigation of complexes containing Mössbauer-active transition metal ions. NFS, which can be regarded as Mössbauer spectroscopy in the time domain, overcomes some limitations of conventional Mössbauer spectroscopy as has been demonstrated especially for bioinorganic compounds. NIS extends the energy range of conventional Mössbauer spectroscopy to the range of molecular vibrations. Since NIS is sensitive only to the mean-square displacement of Mössbauer nuclei it can be used as site-selective vibrational spectroscopy. It complements usefully comparable techniques such as IR or Raman spectroscopy. Examples are given for applications to spin crossover complexes, nitroprusside compounds, heme model complexes and myoglobin.

AB - Nuclear resonant forward scattering (NFS) and nuclear inelastic scattering (NIS) of synchrotron radiation are fairly recent spectroscopic methods for the investigation of complexes containing Mössbauer-active transition metal ions. NFS, which can be regarded as Mössbauer spectroscopy in the time domain, overcomes some limitations of conventional Mössbauer spectroscopy as has been demonstrated especially for bioinorganic compounds. NIS extends the energy range of conventional Mössbauer spectroscopy to the range of molecular vibrations. Since NIS is sensitive only to the mean-square displacement of Mössbauer nuclei it can be used as site-selective vibrational spectroscopy. It complements usefully comparable techniques such as IR or Raman spectroscopy. Examples are given for applications to spin crossover complexes, nitroprusside compounds, heme model complexes and myoglobin.

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DO - 10.1016/j.ccr.2004.03.005

M3 - Scientific review articles

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SN - 0010-8545

VL - 249

SP - 255

EP - 272

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 1-2

ER -

Mössbauer studies of coordination compounds using synchrotron radiation

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