Mössbauer, EPR and susceptibility studies of highly conducting polypyrrole doped with iron chloride

Z. Kucharski; H. Winkler; A. X. Trautwein; C. Budrowski; C. Butzlaff; M. Length

doi:10.1007/BF02401913

Mössbauer, EPR and susceptibility studies of highly conducting polypyrrole doped with iron chloride

Z. Kucharski^*, H. Winkler, A. X. Trautwein, C. Budrowski, C. Butzlaff, M. Length

^*Corresponding author for this work

Institute of Physics

2 Citations (Scopus)

Abstract

The results of Mössbauer, EPR and static magnetic susceptibility measurements on polypyrrole doped with FeCl₃ are presented. They indicate that iron chloride tetrahedra are interacting with the polymer matrix by hydrogen bonding. This interaction increases with dehydration of the samples. The susceptibility showed a maximum near 5 K, which is an indication for antiferromagnetic interaction, probably between paramagnetic iron and polarons.

Original language	English
Journal	Hyperfine Interactions
Volume	69
Issue number	1-4
Pages (from-to)	659-662
Number of pages	4
ISSN	0304-3843
DOIs	https://doi.org/10.1007/BF02401913
Publication status	Published - 01.04.1992

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10.1007/BF02401913

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title = "M{\"o}ssbauer, EPR and susceptibility studies of highly conducting polypyrrole doped with iron chloride",

abstract = "The results of M{\"o}ssbauer, EPR and static magnetic susceptibility measurements on polypyrrole doped with FeCl3 are presented. They indicate that iron chloride tetrahedra are interacting with the polymer matrix by hydrogen bonding. This interaction increases with dehydration of the samples. The susceptibility showed a maximum near 5 K, which is an indication for antiferromagnetic interaction, probably between paramagnetic iron and polarons.",

author = "Z. Kucharski and H. Winkler and Trautwein, {A. X.} and C. Budrowski and C. Butzlaff and M. Length",

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T1 - Mössbauer, EPR and susceptibility studies of highly conducting polypyrrole doped with iron chloride

AU - Kucharski, Z.

AU - Winkler, H.

AU - Trautwein, A. X.

AU - Budrowski, C.

AU - Butzlaff, C.

AU - Length, M.

PY - 1992/4/1

Y1 - 1992/4/1

N2 - The results of Mössbauer, EPR and static magnetic susceptibility measurements on polypyrrole doped with FeCl3 are presented. They indicate that iron chloride tetrahedra are interacting with the polymer matrix by hydrogen bonding. This interaction increases with dehydration of the samples. The susceptibility showed a maximum near 5 K, which is an indication for antiferromagnetic interaction, probably between paramagnetic iron and polarons.

AB - The results of Mössbauer, EPR and static magnetic susceptibility measurements on polypyrrole doped with FeCl3 are presented. They indicate that iron chloride tetrahedra are interacting with the polymer matrix by hydrogen bonding. This interaction increases with dehydration of the samples. The susceptibility showed a maximum near 5 K, which is an indication for antiferromagnetic interaction, probably between paramagnetic iron and polarons.

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U2 - 10.1007/BF02401913

DO - 10.1007/BF02401913

M3 - Journal articles

AN - SCOPUS:0642370830

VL - 69

SP - 659

EP - 662

JO - Hyperfine Interactions

JF - Hyperfine Interactions

SN - 0304-3843

IS - 1-4

ER -

Mössbauer, EPR and susceptibility studies of highly conducting polypyrrole doped with iron chloride

Abstract

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