How “Innocent” Are Pentane‐2,4‐dionebis(S‐alkylisothiosemicarbazonato) Ligands in Biomimetic FeII and FeIV Complexes?*

U. Knof; T. Weyhermuller; T. Wolter; K. Wieghardt; E. Bill; C. Butzlaff; A. X. Trautwein

doi:10.1002/anie.199316351

How “Innocent” Are Pentane‐2,4‐dionebis(S‐alkylisothiosemicarbazonato) Ligands in Biomimetic FeII and FeIV Complexes?*

U. Knof, T. Weyhermuller, T. Wolter, K. Wieghardt, E. Bill, C. Butzlaff, A. X. Trautwein

Institute of Physics

39 Citations (Scopus)

Abstract

Square‐planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons.

Original language	English
Journal	Angewandte Chemie-International Edition in English
Volume	32
Issue number	11
Pages (from-to)	1635-1638
Number of pages	4
DOIs	https://doi.org/10.1002/anie.199316351
Publication status	Published - 01.11.1993

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abstract = " Square‐planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons. ",

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AU - Knof, U.

AU - Weyhermuller, T.

AU - Wolter, T.

AU - Wieghardt, K.

AU - Bill, E.

AU - Butzlaff, C.

AU - Trautwein, A. X.

PY - 1993/11/1

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N2 - Square‐planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons.

AB - Square‐planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons.

U2 - 10.1002/anie.199316351

DO - 10.1002/anie.199316351

M3 - Journal articles

SN - 1521-3773

VL - 32

SP - 1635

EP - 1638

JO - Angewandte Chemie-International Edition in English

JF - Angewandte Chemie-International Edition in English

IS - 11

ER -

How “Innocent” Are Pentane‐2,4‐dionebis(S‐alkylisothiosemicarbazonato) Ligands in Biomimetic FeII and FeIV Complexes?*

Abstract

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