TY - JOUR
T1 - How “Innocent” Are Pentane‐2,4‐dionebis(S‐alkylisothiosemicarbazonato) Ligands in Biomimetic FeII and FeIV Complexes?*
AU - Knof, U.
AU - Weyhermuller, T.
AU - Wolter, T.
AU - Wieghardt, K.
AU - Bill, E.
AU - Butzlaff, C.
AU - Trautwein, A. X.
PY - 1993/11/1
Y1 - 1993/11/1
N2 - Square‐planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons.
AB - Square‐planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons.
U2 - 10.1002/anie.199316351
DO - 10.1002/anie.199316351
M3 - Journal articles
SN - 1521-3773
VL - 32
SP - 1635
EP - 1638
JO - Angewandte Chemie-International Edition in English
JF - Angewandte Chemie-International Edition in English
IS - 11
ER -
