Square‐planar FeIV complexes with a ground state of S = 1 can stabilize the 14π electron system L3−. Treatment with π acceptors such as phosphanes, cyanides, or methylimidazole produces diamagnetic, octahedral FeII complexes (S = 0) containing the monoanion L−, which has 12π electrons.
|Journal||Angewandte Chemie-International Edition in English|
|Number of pages||4|
|Publication status||Published - 01.11.1993|