High-spin low-spin transition

H. Grünsteudel; H. Paulsen; H. Winkler; A. X. Trautwein; H. Toftlund

doi:10.1023/A:1017056831002

High-spin low-spin transition

H. Grünsteudel, H. Paulsen, H. Winkler, A. X. Trautwein^*, H. Toftlund

^*Corresponding author for this work

Institute of Physics

University of Southern Denmark

6 Citations (Scopus)

Abstract

Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)₂] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.

Original language	English
Journal	Hyperfine Interactions
Volume	123-124
Issue number	1-4
Pages (from-to)	841-846
Number of pages	6
ISSN	0304-3843
DOIs	https://doi.org/10.1023/A:1017056831002
Publication status	Published - 01.12.1999

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1023/A:1017056831002

Cite this

@article{1c5ee6ee7cdc41b3a686127934100eaf,

title = "High-spin low-spin transition",

abstract = "Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)2] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.",

author = "H. Gr{\"u}nsteudel and H. Paulsen and H. Winkler and Trautwein, {A. X.} and H. Toftlund",

year = "1999",

month = dec,

day = "1",

doi = "10.1023/A:1017056831002",

language = "English",

volume = "123-124",

pages = "841--846",

journal = "Hyperfine Interactions",

issn = "0304-3843",

number = "1-4",

}

TY - JOUR

T1 - High-spin low-spin transition

AU - Grünsteudel, H.

AU - Paulsen, H.

AU - Winkler, H.

AU - Trautwein, A. X.

AU - Toftlund, H.

PY - 1999/12/1

Y1 - 1999/12/1

N2 - Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)2] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.

AB - Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)2] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.

UR - http://www.scopus.com/inward/record.url?scp=0043046074&partnerID=8YFLogxK

U2 - 10.1023/A:1017056831002

DO - 10.1023/A:1017056831002

M3 - Journal articles

AN - SCOPUS:0043046074

SN - 0304-3843

VL - 123-124

SP - 841

EP - 846

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1-4

ER -

High-spin low-spin transition

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this