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Delocalization over the heme and the axial ligands of one of the two oxidizing equivalents stored above the ferric state in the peroxidase and catalase Compound-I intermediates: Indirect participation of the proximal axial ligand of iron in the oxidation reactions catalyzed by heme-based peroxidases and catalases?

Raymond Weiss*, Dominique Mandon, Thomas Wolter, Alfred X. Trautwein, Markus Müther, Eckhard Bill, Avram Gold, Karupiah Jayaraj, James Terner

*Corresponding author for this work
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Biochemistry, Genetics and Molecular Biology