Abstract
We have applied Mössbauer- and EPR spectroscopy to [(Cl)Fe(IV)=O(TMP)̇] which is a synthetic analog for compound I of the heme peroxidases. The temperature- and field-dependent Mössbauer- and EPR spectra were analyzed within the spin-Hamiltonian formalism. Spectral simulations with a unique parameter set are prohibited due to the fact that several of the spin-Hamiltonian parameters cannot be determined independently and, therefore, are covariant. Theoretical considerations are discussed to reduce the allowed parameter space.
Original language | English |
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Journal | Bulletin de la Societe Chimique de France |
Volume | 133 |
Issue number | 7-8 |
Pages (from-to) | 703-710 |
Number of pages | 8 |
ISSN | 0037-8968 |
Publication status | Published - 01.12.1996 |