ChemInform Abstract: Preparation of Metal‐Sulfur‐Clusters by Simple Reaction of Metal‐Salts with H2S: R2(NH4)(Cu3S12), R2(Cu4S12)·CH3CN, R2(Cu4S12.8), R2(Fe2S2(S5)2), R2(Fe4S4Br4),R2(Fe4S4Br2Cl2), R2(Fe4S4Cl4), R2(Fe2S2Cl4) (R: PPh4) and (Fe(DMF)6) (Fe2S2Cl4).

A. Müller, N. H. Schladerbeck, E. Krickemeyer, H. Bogge, K. Schmitz, E. Bill, A. X. Trautwein

Abstract

The title compounds (III), (V), (VI), (VII), (X), and (XIII) are prepared by the simple methods outlined in the scheme and characterized by IR, Raman, and Moessbauer spectroscopy and XRD.
Original languageEnglish
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume570
Issue number3
Pages (from-to)7-36
Number of pages30
ISSN0044-2313
DOIs
Publication statusPublished - 04.07.1989

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