TY - JOUR
T1 - Characterization of an Oxo(porphyrinato)manganese(IV) Complex by X‐ray Absorption Spectroscopy
AU - Charnock, John M.
AU - Garner, C. David
AU - Trautwein, Alfred X.
AU - Bill, Eckard
AU - Winkler, Heiner
AU - Ayougou, Khadija
AU - Mandon, Dominique
AU - Weiss, Raymond
PY - 1995/2/21
Y1 - 1995/2/21
N2 - The MnIVO unit in the five‐coordinate oxo(porphyrinato)manganese(IV) complex 2, which is formed by oxidation of the bromo(porphyrinato)manganese(III) complex 1 with potassium peroxycarbonate, was characterized by X‐ray absorption spectroscopy. The relatively long MnO bond (1.69±0.03 Å) is probably attributable to the high‐spin state and the low polarizability of the half‐filled t 2g3 subshell of high‐spin MnIV. (Figure Presented.)
AB - The MnIVO unit in the five‐coordinate oxo(porphyrinato)manganese(IV) complex 2, which is formed by oxidation of the bromo(porphyrinato)manganese(III) complex 1 with potassium peroxycarbonate, was characterized by X‐ray absorption spectroscopy. The relatively long MnO bond (1.69±0.03 Å) is probably attributable to the high‐spin state and the low polarizability of the half‐filled t 2g3 subshell of high‐spin MnIV. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748222355&partnerID=8YFLogxK
U2 - 10.1002/anie.199503431
DO - 10.1002/anie.199503431
M3 - Journal articles
AN - SCOPUS:33748222355
SN - 0570-0833
VL - 34
SP - 343
EP - 346
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 3
ER -
