Abstract
Nuclear forward scattering (NFS) of synchrotron radiation was applied to investigate the electronic and magnetic properties of (i) the diamagnetic "picket-fence" porphyrin FeO2(SC6HF4)(TPpivP), which is a model for oxygenated hemoglobin and myoglobin and (ii) the paramagnetic "picket-fence" porphyrin [Fe(CH3COOH)(TPpivP)]-, which is a model for the ferrous state of the prosthetic group, termed P460, of the multi-heme enzyme hydroxylamine oxidoreductase from the bacterium Nitrosomonas europeae.
| Original language | English |
|---|---|
| Journal | Hyperfine Interactions |
| Volume | 123-124 |
| Issue number | 1-4 |
| Pages (from-to) | 561-570 |
| Number of pages | 10 |
| ISSN | 0304-3843 |
| DOIs | |
| Publication status | Published - 01.12.1999 |
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SDG 9 Industry, Innovation, and Infrastructure
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