Abstract
Nuclear forward scattering (NFS) of synchrotron radiation was applied to investigate the electronic and magnetic properties of (i) the diamagnetic "picket-fence" porphyrin FeO2(SC6HF4)(TPpivP), which is a model for oxygenated hemoglobin and myoglobin and (ii) the paramagnetic "picket-fence" porphyrin [Fe(CH3COOH)(TPpivP)]-, which is a model for the ferrous state of the prosthetic group, termed P460, of the multi-heme enzyme hydroxylamine oxidoreductase from the bacterium Nitrosomonas europeae.
Original language | English |
---|---|
Journal | Hyperfine Interactions |
Volume | 123-124 |
Issue number | 1-4 |
Pages (from-to) | 561-570 |
Number of pages | 10 |
ISSN | 0304-3843 |
DOIs | |
Publication status | Published - 01.12.1999 |