Anisotropic nuclear inelastic scattering of an iron(II) molecular crystal

H. Paulsen; R. Benda; C. Herta; V. Schünemann; A. I. Chumakov; L. Duelund; H. Winkler; H. Toftlund; A. X. Trautwein

doi:10.1103/PhysRevLett.86.1351

Anisotropic nuclear inelastic scattering of an iron(II) molecular crystal

H. Paulsen^*, R. Benda, C. Herta, V. Schünemann, A. I. Chumakov, L. Duelund, H. Winkler, H. Toftlund, A. X. Trautwein

^*Corresponding author for this work

Institute of Physics

60 Citations (Scopus)

Abstract

Nuclear inelastic scattering (NIS) measurements were carried out to account for the angular dependence of the vibrational modes of a molecular crystal. For this purpose, the iron(II) spin-crossover complex [Fe(tptMetame)](ClO₄)₂ (tptMetame=1,1,1-tris{[N-(2-pyridylmethyl)]-N- methylamino]methyl}ethane) was selected. As a result, it was possible to identify for the first time individual anisotropic normal modes of vibration of a molecular crystal.

Original language	English
Journal	Physical Review Letters
Volume	86
Issue number	7
Pages (from-to)	1351-1354
Number of pages	4
ISSN	0031-9007
DOIs	https://doi.org/10.1103/PhysRevLett.86.1351
Publication status	Published - 12.02.2001

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abstract = "Nuclear inelastic scattering (NIS) measurements were carried out to account for the angular dependence of the vibrational modes of a molecular crystal. For this purpose, the iron(II) spin-crossover complex [Fe(tptMetame)](ClO4)2 (tptMetame=1,1,1-tris{[N-(2-pyridylmethyl)]-N- methylamino]methyl}ethane) was selected. As a result, it was possible to identify for the first time individual anisotropic normal modes of vibration of a molecular crystal.",

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T1 - Anisotropic nuclear inelastic scattering of an iron(II) molecular crystal

AU - Paulsen, H.

AU - Benda, R.

AU - Herta, C.

AU - Schünemann, V.

AU - Chumakov, A. I.

AU - Duelund, L.

AU - Winkler, H.

AU - Toftlund, H.

AU - Trautwein, A. X.

PY - 2001/2/12

Y1 - 2001/2/12

N2 - Nuclear inelastic scattering (NIS) measurements were carried out to account for the angular dependence of the vibrational modes of a molecular crystal. For this purpose, the iron(II) spin-crossover complex [Fe(tptMetame)](ClO4)2 (tptMetame=1,1,1-tris{[N-(2-pyridylmethyl)]-N- methylamino]methyl}ethane) was selected. As a result, it was possible to identify for the first time individual anisotropic normal modes of vibration of a molecular crystal.

AB - Nuclear inelastic scattering (NIS) measurements were carried out to account for the angular dependence of the vibrational modes of a molecular crystal. For this purpose, the iron(II) spin-crossover complex [Fe(tptMetame)](ClO4)2 (tptMetame=1,1,1-tris{[N-(2-pyridylmethyl)]-N- methylamino]methyl}ethane) was selected. As a result, it was possible to identify for the first time individual anisotropic normal modes of vibration of a molecular crystal.

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DO - 10.1103/PhysRevLett.86.1351

M3 - Journal articles

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VL - 86

SP - 1351

EP - 1354

JO - Physical Review Letters

JF - Physical Review Letters

IS - 7

ER -

Anisotropic nuclear inelastic scattering of an iron(II) molecular crystal

Abstract

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