Abstract
For the formation of ternary “super complexes” the character of the participating anions is of decisive importance. In the polymeric 1:1:1 complexes of dibenzo‐18‐crown‐6, potassium iodide, and thiourea, K+ is situated in the center of the crown ether cavity and is additionally coordinated by I−; thiourea forms polymeric chains linked by H‐bridges. Only readily polarizable ions such as I − are capable of functioning as connecting links between crown ether complexes and thiourea chain.
| Original language | English |
|---|---|
| Journal | Angewandte Chemie International Edition in English |
| Volume | 20 |
| Issue number | 12 |
| Pages (from-to) | 1045-1046 |
| Number of pages | 2 |
| ISSN | 0570-0833 |
| DOIs | |
| Publication status | Published - 12.1981 |
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Research Areas and Centers
- Academic Focus: Center for Infection and Inflammation Research (ZIEL)
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