A Novel Hexanuclear FeIII‐cis‐Inositolato Complex as a Model for FeIII–Polyol Interactions in Aqueous Solution

Kaspar Hegetschweiler; Lorenza Hausherr‐Primo; Willem H. Koppenol; Volker Gramlich; Léon Odier; Wolfram Meyer; Heiner Winkler; Alfred X. Trautwein

doi:10.1002/anie.199522421

A Novel Hexanuclear Fe^III‐cis‐Inositolato Complex as a Model for Fe^III–Polyol Interactions in Aqueous Solution

Kaspar Hegetschweiler^*, Lorenza Hausherr‐Primo, Willem H. Koppenol, Volker Gramlich, Léon Odier, Wolfram Meyer, Heiner Winkler, Alfred X. Trautwein

^*Corresponding author for this work

Institute of Physics

29 Citations (Scopus)

Abstract

Corner‐sharing, edge‐sharing, and face‐sharing FeO_x polyhedra (x = 5,6) form a cyclic complex anion in K₅[OFe₆{(ino)₆21H}]·14.5 H₂O (ino = cis‐inositol), the first structurally characterized polyolato(oxo)ferrate from aqueous solution. The synthesis is as simple as the structure is complicated (see diagram). (Figure Presented.)

Original language	English
Journal	Angewandte Chemie International Edition in English
Volume	34
Issue number	20
Pages (from-to)	2242-2243
Number of pages	2
ISSN	0570-0833
DOIs	https://doi.org/10.1002/anie.199522421
Publication status	Published - 03.11.1995

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10.1002/anie.199522421

Cite this

@article{79ade8c79c2d40c3a7fa55e1f3d4d021,

title = "A Novel Hexanuclear FeIII‐cis‐Inositolato Complex as a Model for FeIII–Polyol Interactions in Aqueous Solution",

abstract = "Corner‐sharing, edge‐sharing, and face‐sharing FeOx polyhedra (x = 5,6) form a cyclic complex anion in K5[OFe6\{(ino)621H\}]·14.5 H2O (ino = cis‐inositol), the first structurally characterized polyolato(oxo)ferrate from aqueous solution. The synthesis is as simple as the structure is complicated (see diagram). (Figure Presented.)",

author = "Kaspar Hegetschweiler and Lorenza Hausherr‐Primo and Koppenol, \{Willem H.\} and Volker Gramlich and L{\'e}on Odier and Wolfram Meyer and Heiner Winkler and Trautwein, \{Alfred X.\}",

year = "1995",

month = nov,

day = "3",

doi = "10.1002/anie.199522421",

language = "English",

volume = "34",

pages = "2242--2243",

journal = "Angewandte Chemie International Edition in English",

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A Novel Hexanuclear Fe^III‐cis‐Inositolato Complex as a Model for Fe^III–Polyol Interactions in Aqueous Solution. / Hegetschweiler, Kaspar; Hausherr‐Primo, Lorenza; Koppenol, Willem H. et al.
In: Angewandte Chemie International Edition in English, Vol. 34, No. 20, 03.11.1995, p. 2242-2243.

Research output: Journal Articles › Journal articles › Research › peer-review

TY - JOUR

T1 - A Novel Hexanuclear FeIII‐cis‐Inositolato Complex as a Model for FeIII–Polyol Interactions in Aqueous Solution

AU - Hegetschweiler, Kaspar

AU - Hausherr‐Primo, Lorenza

AU - Koppenol, Willem H.

AU - Gramlich, Volker

AU - Odier, Léon

AU - Meyer, Wolfram

AU - Winkler, Heiner

AU - Trautwein, Alfred X.

PY - 1995/11/3

Y1 - 1995/11/3

N2 - Corner‐sharing, edge‐sharing, and face‐sharing FeOx polyhedra (x = 5,6) form a cyclic complex anion in K5[OFe6{(ino)621H}]·14.5 H2O (ino = cis‐inositol), the first structurally characterized polyolato(oxo)ferrate from aqueous solution. The synthesis is as simple as the structure is complicated (see diagram). (Figure Presented.)

AB - Corner‐sharing, edge‐sharing, and face‐sharing FeOx polyhedra (x = 5,6) form a cyclic complex anion in K5[OFe6{(ino)621H}]·14.5 H2O (ino = cis‐inositol), the first structurally characterized polyolato(oxo)ferrate from aqueous solution. The synthesis is as simple as the structure is complicated (see diagram). (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33749111494

U2 - 10.1002/anie.199522421

DO - 10.1002/anie.199522421

M3 - Journal articles

AN - SCOPUS:33749111494

SN - 0570-0833

VL - 34

SP - 2242

EP - 2243

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 20