A Novel Hexanuclear FeIII‐cis‐Inositolato Complex as a Model for FeIII–Polyol Interactions in Aqueous Solution

Kaspar Hegetschweiler*, Lorenza Hausherr‐Primo, Willem H. Koppenol, Volker Gramlich, Léon Odier, Wolfram Meyer, Heiner Winkler, Alfred X. Trautwein

*Corresponding author for this work
27 Citations (Scopus)

Abstract

Corner‐sharing, edge‐sharing, and face‐sharing FeOx polyhedra (x = 5,6) form a cyclic complex anion in K5[OFe6{(ino)621H}]·14.5 H2O (ino = cis‐inositol), the first structurally characterized polyolato(oxo)ferrate from aqueous solution. The synthesis is as simple as the structure is complicated (see diagram). (Figure Presented.)

Original languageEnglish
JournalAngewandte Chemie International Edition in English
Volume34
Issue number20
Pages (from-to)2242-2243
Number of pages2
ISSN0570-0833
DOIs
Publication statusPublished - 03.11.1995

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