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A new type of supramolecular compound: Molybdenum-oxide-based composites consisting of magnetic nanocapsules with encapsulated Keggin-ion electron reservoirs cross-linked to a two-dimensional network

  • Achim Muller*
  • , Samar K. Das
  • , Paul Kogerler
  • , Hartmut Bogge
  • , Marc Schmidtmann
  • , Alfred X. Trautwein
  • , Volker Schunemann
  • , Erich Krickemeyer
  • , Wilhelm Preetz
  • *Corresponding author for this work
  • Bielefeld University
  • University of Kiel

Abstract

Nanosized metal-oxide-based composites - novel supramolecular entities - have been assembled and even cross-linked under one-pot conditions. The supramolecular entity (see picture) consists of a paramagnetic icosahedral capsule of the type {Mo 72/(VI)Fe 30/(III)} as a host which encloses a potential electron-reservoir noncovalently bonded guest, the reduced Keggin cluster [H 2PMo 12O 40] 3-.

Original languageEnglish
JournalAngewandte Chemie - International Edition
Volume39
Issue number19
Pages (from-to)3414-3417
Number of pages4
ISSN1433-7851
DOIs
Publication statusPublished - 02.10.2000

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 9 - Industry, Innovation, and Infrastructure
    SDG 9 Industry, Innovation, and Infrastructure

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