A new type of supramolecular compound: Molybdenum-oxide-based composites consisting of magnetic nanocapsules with encapsulated Keggin-ion electron reservoirs cross-linked to a two-dimensional network

Achim Muller*, Samar K. Das, Paul Kogerler, Hartmut Bogge, Marc Schmidtmann, Alfred X. Trautwein, Volker Schunemann, Erich Krickemeyer, Wilhelm Preetz

*Corresponding author for this work
53 Citations (Scopus)

Abstract

Nanosized metal-oxide-based composites - novel supramolecular entities - have been assembled and even cross-linked under one-pot conditions. The supramolecular entity (see picture) consists of a paramagnetic icosahedral capsule of the type {Mo 72/(VI)Fe 30/(III)} as a host which encloses a potential electron-reservoir noncovalently bonded guest, the reduced Keggin cluster [H 2PMo 12O 40] 3-.

Original languageEnglish
JournalAngewandte Chemie - International Edition
Volume39
Issue number19
Pages (from-to)3414-3417
Number of pages4
ISSN1433-7851
DOIs
Publication statusPublished - 02.10.2000

Fingerprint

Dive into the research topics of 'A new type of supramolecular compound: Molybdenum-oxide-based composites consisting of magnetic nanocapsules with encapsulated Keggin-ion electron reservoirs cross-linked to a two-dimensional network'. Together they form a unique fingerprint.

Cite this