A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration

Andrea Niemann; Ursula Bossek; Karl Wieghardt; Christian Butzlaff; Alfred X. Trautwein; Bernhard Nuber

doi:10.1002/anie.199203111

A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d³–d³ Electronic Configuration

Andrea Niemann, Ursula Bossek, Karl Wieghardt^*, Christian Butzlaff, Alfred X. Trautwein, Bernhard Nuber

^*Corresponding author for this work

Institute of Physics

69 Citations (Scopus)

Abstract

A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d³‐d³ electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.

Original language	English
Journal	Angewandte Chemie International Edition in English
Volume	31
Issue number	3
Pages (from-to)	311-313
Number of pages	3
ISSN	0570-0833
DOIs	https://doi.org/10.1002/anie.199203111
Publication status	Published - 01.03.1992

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title = "A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration",

abstract = "A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.",

author = "Andrea Niemann and Ursula Bossek and Karl Wieghardt and Christian Butzlaff and Trautwein, \{Alfred X.\} and Bernhard Nuber",

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T1 - A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration

AU - Niemann, Andrea

AU - Bossek, Ursula

AU - Wieghardt, Karl

AU - Butzlaff, Christian

AU - Trautwein, Alfred X.

AU - Nuber, Bernhard

PY - 1992/3/1

Y1 - 1992/3/1

N2 - A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.

AB - A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.

UR - https://www.scopus.com/pages/publications/33748228883

U2 - 10.1002/anie.199203111

DO - 10.1002/anie.199203111

M3 - Journal articles

AN - SCOPUS:33748228883

SN - 0570-0833

VL - 31

SP - 311

EP - 313

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 3

ER -

A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d³–d³ Electronic Configuration

Abstract

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