A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration

Andrea Niemann, Ursula Bossek, Karl Wieghardt*, Christian Butzlaff, Alfred X. Trautwein, Bernhard Nuber

*Corresponding author for this work
46 Citations (Scopus)

Abstract

A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.

Original languageEnglish
JournalAngewandte Chemie International Edition in English
Volume31
Issue number3
Pages (from-to)311-313
Number of pages3
ISSN0570-0833
DOIs
Publication statusPublished - 01.03.1992

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