TY - JOUR
T1 - A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration
AU - Niemann, Andrea
AU - Bossek, Ursula
AU - Wieghardt, Karl
AU - Butzlaff, Christian
AU - Trautwein, Alfred X.
AU - Nuber, Bernhard
PY - 1992/3/1
Y1 - 1992/3/1
N2 - A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.
AB - A through‐space interaction and not superexchange of the bridging ligands explains the antiferromagnetic coupling in dinuclear face‐sharing octahedral complexes with d3‐d3 electronic configuration. The metal‐metal distance is the only relevant structural parameter for the spin‐exchange coupling constants of a series of V 2II, Cr 2III, and Mn 2IV complexes.
UR - http://www.scopus.com/inward/record.url?scp=33748228883&partnerID=8YFLogxK
U2 - 10.1002/anie.199203111
DO - 10.1002/anie.199203111
M3 - Journal articles
AN - SCOPUS:33748228883
VL - 31
SP - 311
EP - 313
JO - Angewandte Chemie (International Edition in English)
JF - Angewandte Chemie (International Edition in English)
SN - 0570-0833
IS - 3
ER -