A neutral, triple-helical, trinuclear, oxo-centered mixed-valence iron complex

Rolf W. Saalfrank; Stefan Trummer; Harald Krautscheid; Volker Schünemann; Alfred X. Trautwein; Stefan Hien; Christian Stadler; Jörg Daub

doi:10.1002/anie.199622061

A neutral, triple-helical, trinuclear, oxo-centered mixed-valence iron complex

Rolf W. Saalfrank^*
, Stefan Trummer
, Harald Krautscheid
, Volker Schünemann
, Alfred X. Trautwein
, Stefan Hien
, Christian Stadler
, Jörg Daub

^*Corresponding author for this work

Institute of Physics

University of Erlangen–Nuremberg
University of Karlsruhe

42 Citations (Scopus)

Abstract

Reminiscent of a windmill, the novel triple‐helicate [(Fe^III)₂Fe^IIOL³] 1, a neutral oxo‐centered mixed‐valence complex, is formed in a one‐pot reaction by self‐assembly. The pentadentate ligand L acts in a tritopic fashion and connects the three iron ions in a triangular plane. At the center of 1 lies μ₃‐O²‐ ion. The structural similarity of 1 with trinuclear carboxylatoiron complexes is striking.

Original language	English
Journal	Angewandte Chemie (International Edition in English)
Volume	35
Issue number	19
Pages (from-to)	2206-2208
Number of pages	3
ISSN	0570-0833
DOIs	https://doi.org/10.1002/anie.199622061
Publication status	Published - 01.01.1996

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10.1002/anie.199622061

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title = "A neutral, triple-helical, trinuclear, oxo-centered mixed-valence iron complex",

abstract = "Reminiscent of a windmill, the novel triple‐helicate [(FeIII)2FeIIOL3] 1, a neutral oxo‐centered mixed‐valence complex, is formed in a one‐pot reaction by self‐assembly. The pentadentate ligand L acts in a tritopic fashion and connects the three iron ions in a triangular plane. At the center of 1 lies μ3‐O2‐ ion. The structural similarity of 1 with trinuclear carboxylatoiron complexes is striking. ",

author = "Saalfrank, \{Rolf W.\} and Stefan Trummer and Harald Krautscheid and Volker Sch{\"u}nemann and Trautwein, \{Alfred X.\} and Stefan Hien and Christian Stadler and J{\"o}rg Daub",

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month = jan,

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doi = "10.1002/anie.199622061",

language = "English",

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T1 - A neutral, triple-helical, trinuclear, oxo-centered mixed-valence iron complex

AU - Saalfrank, Rolf W.

AU - Trummer, Stefan

AU - Krautscheid, Harald

AU - Schünemann, Volker

AU - Trautwein, Alfred X.

AU - Hien, Stefan

AU - Stadler, Christian

AU - Daub, Jörg

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Reminiscent of a windmill, the novel triple‐helicate [(FeIII)2FeIIOL3] 1, a neutral oxo‐centered mixed‐valence complex, is formed in a one‐pot reaction by self‐assembly. The pentadentate ligand L acts in a tritopic fashion and connects the three iron ions in a triangular plane. At the center of 1 lies μ3‐O2‐ ion. The structural similarity of 1 with trinuclear carboxylatoiron complexes is striking.

AB - Reminiscent of a windmill, the novel triple‐helicate [(FeIII)2FeIIOL3] 1, a neutral oxo‐centered mixed‐valence complex, is formed in a one‐pot reaction by self‐assembly. The pentadentate ligand L acts in a tritopic fashion and connects the three iron ions in a triangular plane. At the center of 1 lies μ3‐O2‐ ion. The structural similarity of 1 with trinuclear carboxylatoiron complexes is striking.

UR - https://www.scopus.com/pages/publications/0030445477

U2 - 10.1002/anie.199622061

DO - 10.1002/anie.199622061

M3 - Journal articles

AN - SCOPUS:0030445477

SN - 0570-0833

VL - 35

SP - 2206

EP - 2208

JO - Angewandte Chemie (International Edition in English)

JF - Angewandte Chemie (International Edition in English)

IS - 19

ER -

A neutral, triple-helical, trinuclear, oxo-centered mixed-valence iron complex

Abstract

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