TY - JOUR
T1 - A neutral, triple-helical, trinuclear, oxo-centered mixed-valence iron complex
AU - Saalfrank, Rolf W.
AU - Trummer, Stefan
AU - Krautscheid, Harald
AU - Schünemann, Volker
AU - Trautwein, Alfred X.
AU - Hien, Stefan
AU - Stadler, Christian
AU - Daub, Jörg
PY - 1996/1/1
Y1 - 1996/1/1
N2 - Reminiscent of a windmill, the novel triple‐helicate [(FeIII)2FeIIOL3] 1,
a neutral oxo‐centered mixed‐valence complex, is formed in a one‐pot
reaction by self‐assembly. The pentadentate ligand L acts in a tritopic
fashion and connects the three iron ions in a triangular plane. At the
center of 1 lies μ3‐O2‐ ion. The structural similarity of 1 with trinuclear carboxylatoiron complexes is striking.
AB - Reminiscent of a windmill, the novel triple‐helicate [(FeIII)2FeIIOL3] 1,
a neutral oxo‐centered mixed‐valence complex, is formed in a one‐pot
reaction by self‐assembly. The pentadentate ligand L acts in a tritopic
fashion and connects the three iron ions in a triangular plane. At the
center of 1 lies μ3‐O2‐ ion. The structural similarity of 1 with trinuclear carboxylatoiron complexes is striking.
UR - http://www.scopus.com/inward/record.url?scp=0030445477&partnerID=8YFLogxK
U2 - 10.1002/anie.199622061
DO - 10.1002/anie.199622061
M3 - Journal articles
AN - SCOPUS:0030445477
SN - 0570-0833
VL - 35
SP - 2206
EP - 2208
JO - Angewandte Chemie (International Edition in English)
JF - Angewandte Chemie (International Edition in English)
IS - 19
ER -
