A diferric peroxo complex with an unprecedented spin configuration: An S = 2 system arising from an S = 5/2, 1/2 pair

Helga Hummel; Yasmina Mekmouche; Carole Duboc-Toia; Raymond Y.N. Ho; Lawrence Que; Volker Schünemann; Fabrice Thomas; Alfred X. Trautwein; Colette Lebrun; Marc Fontecave; Stéphane Ménage

doi:10.1002/1521-3773(20020215)41:4<617::AID-ANIE617>3.0.CO;2-Q

A diferric peroxo complex with an unprecedented spin configuration: An S = 2 system arising from an S = 5/2, 1/2 pair

Helga Hummel, Yasmina Mekmouche, Carole Duboc-Toia, Raymond Y.N. Ho, Lawrence Que, Volker Schünemann, Fabrice Thomas, Alfred X. Trautwein, Colette Lebrun, Marc Fontecave^*, Stéphane Ménage

^*Corresponding author for this work

Institute of Physics

11 Citations (Scopus)

Abstract

In a spin: Transient peroxo iron complexes have been characterized by the means of Mössbauer and HF-EPR spectroscopies. Complex 1 has an unexpected S = 2 ground state resulting from the coupling between the S = 5/2 and S = 1/2 iron(III) ions.

Original language	English
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	4
Pages (from-to)	617-620
Number of pages	4
ISSN	1433-7851
DOIs	https://doi.org/10.1002/1521-3773(20020215)41:4<617::AID-ANIE617>3.0.CO;2-Q
Publication status	Published - 15.02.2002

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10.1002/1521-3773(20020215)41:4<617::AID-ANIE617>3.0.CO;2-Q

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Hummel, H., Mekmouche, Y., Duboc-Toia, C., Ho, R. Y. N., Que, L., Schünemann, V., Thomas, F., Trautwein, A. X., Lebrun, C., Fontecave, M., & Ménage, S. (2002). A diferric peroxo complex with an unprecedented spin configuration: An S = 2 system arising from an S = 5/2, 1/2 pair. Angewandte Chemie - International Edition, 41(4), 617-620. https://doi.org/10.1002/1521-3773(20020215)41:4<617::AID-ANIE617>3.0.CO;2-Q

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abstract = "In a spin: Transient peroxo iron complexes have been characterized by the means of M{\"o}ssbauer and HF-EPR spectroscopies. Complex 1 has an unexpected S = 2 ground state resulting from the coupling between the S = 5/2 and S = 1/2 iron(III) ions.",

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Hummel, H, Mekmouche, Y, Duboc-Toia, C, Ho, RYN, Que, L, Schünemann, V, Thomas, F, Trautwein, AX, Lebrun, C, Fontecave, M & Ménage, S 2002, 'A diferric peroxo complex with an unprecedented spin configuration: An S = 2 system arising from an S = 5/2, 1/2 pair', Angewandte Chemie - International Edition, vol. 41, no. 4, pp. 617-620. https://doi.org/10.1002/1521-3773(20020215)41:4<617::AID-ANIE617>3.0.CO;2-Q

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T1 - A diferric peroxo complex with an unprecedented spin configuration: An S = 2 system arising from an S = 5/2, 1/2 pair

AU - Hummel, Helga

AU - Mekmouche, Yasmina

AU - Duboc-Toia, Carole

AU - Ho, Raymond Y.N.

AU - Que, Lawrence

AU - Schünemann, Volker

AU - Thomas, Fabrice

AU - Trautwein, Alfred X.

AU - Lebrun, Colette

AU - Fontecave, Marc

AU - Ménage, Stéphane

PY - 2002/2/15

Y1 - 2002/2/15

N2 - In a spin: Transient peroxo iron complexes have been characterized by the means of Mössbauer and HF-EPR spectroscopies. Complex 1 has an unexpected S = 2 ground state resulting from the coupling between the S = 5/2 and S = 1/2 iron(III) ions.

AB - In a spin: Transient peroxo iron complexes have been characterized by the means of Mössbauer and HF-EPR spectroscopies. Complex 1 has an unexpected S = 2 ground state resulting from the coupling between the S = 5/2 and S = 1/2 iron(III) ions.

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VL - 41

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 4

ER -

A diferric peroxo complex with an unprecedented spin configuration: An S = 2 system arising from an S = 5/2, 1/2 pair

Abstract

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