(1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): A Model for the Iron-Sulfur Center in Nitrile Hydratase from Breribacterium, sp

Thomas Beissel; Kai Silke Bürger; Gottfried Voigt; Karl Wieghardt; Christian Butzlaff; Alfred X. Trautwein

doi:10.1021/ic00054a002

(1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): A Model for the Iron-Sulfur Center in Nitrile Hydratase from Breribacterium, sp

Thomas Beissel, Kai Silke Bürger, Gottfried Voigt, Karl Wieghardt^*, Christian Butzlaff, Alfred X. Trautwein

^*Corresponding author for this work

Institute of Physics

Ruhr-University Bochum

76 Citations (Scopus)

Abstract

Stable six-coordinate iron(III) complexes of the pendant arm macrocycles 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane and 1,4,7-tris(mercaptopropyl)-1,4,7-triazacyclononane each of which provide a fac-N3S3 donor set have been synthesized and characterized by UV-vis and ESR spectroscopy. These complexes serve as a structural model for the bacterial enzyme nitrile hydratase from Brevibacterium, sp.

Original language	English
Journal	Inorganic Chemistry
Volume	32
Issue number	2
Pages (from-to)	124-126
Number of pages	3
ISSN	0020-1669
DOIs	https://doi.org/10.1021/ic00054a002
Publication status	Published - 01.01.1993

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title = "(1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): A Model for the Iron-Sulfur Center in Nitrile Hydratase from Breribacterium, sp",

abstract = "Stable six-coordinate iron(III) complexes of the pendant arm macrocycles 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane and 1,4,7-tris(mercaptopropyl)-1,4,7-triazacyclononane each of which provide a fac-N3S3 donor set have been synthesized and characterized by UV-vis and ESR spectroscopy. These complexes serve as a structural model for the bacterial enzyme nitrile hydratase from Brevibacterium, sp. ",

author = "Thomas Beissel and B{\"u}rger, \{Kai Silke\} and Gottfried Voigt and Karl Wieghardt and Christian Butzlaff and Trautwein, \{Alfred X.\}",

year = "1993",

month = jan,

day = "1",

doi = "10.1021/ic00054a002",

language = "English",

volume = "32",

pages = "124--126",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - (1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): A Model for the Iron-Sulfur Center in Nitrile Hydratase from Breribacterium, sp

AU - Beissel, Thomas

AU - Bürger, Kai Silke

AU - Voigt, Gottfried

AU - Wieghardt, Karl

AU - Butzlaff, Christian

AU - Trautwein, Alfred X.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Stable six-coordinate iron(III) complexes of the pendant arm macrocycles 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane and 1,4,7-tris(mercaptopropyl)-1,4,7-triazacyclononane each of which provide a fac-N3S3 donor set have been synthesized and characterized by UV-vis and ESR spectroscopy. These complexes serve as a structural model for the bacterial enzyme nitrile hydratase from Brevibacterium, sp.

AB - Stable six-coordinate iron(III) complexes of the pendant arm macrocycles 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane and 1,4,7-tris(mercaptopropyl)-1,4,7-triazacyclononane each of which provide a fac-N3S3 donor set have been synthesized and characterized by UV-vis and ESR spectroscopy. These complexes serve as a structural model for the bacterial enzyme nitrile hydratase from Brevibacterium, sp.

UR - https://www.scopus.com/pages/publications/0001551739

U2 - 10.1021/ic00054a002

DO - 10.1021/ic00054a002

M3 - Journal articles

AN - SCOPUS:0001551739

SN - 0020-1669

VL - 32

SP - 124

EP - 126

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

(1,4,7-Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane)iron(III): A Model for the Iron-Sulfur Center in Nitrile Hydratase from Breribacterium, sp

Abstract

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