X-ray and57Fe Mössbauer study on a Fe(III) complex of 2-acetyl-1,3-indandione

Anife Ahmedova; Ventzislav Rusanov; Alan Hazell; Juliusz A. Wolny; Georgi Gochev; Alfred X. Trautwein; Mariana Mitewa

doi:10.1016/j.ica.2006.01.011

X-ray and57Fe Mössbauer study on a Fe(III) complex of 2-acetyl-1,3-indandione

Anife Ahmedova, Ventzislav Rusanov, Alan Hazell, Juliusz A. Wolny, Georgi Gochev, Alfred X. Trautwein, Mariana Mitewa

Institut für Physik

12 Zitate (Scopus)

Abstract

Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed Mössbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin-spin magnetic relaxation process. Two different approaches for computer processing of the experimental Mössbauer spectra are considered. © 2006 Elsevier B.V. All rights reserved.

Originalsprache	Englisch
Zeitschrift	Inorganica Chimica Acta
Jahrgang	359
Ausgabenummer	10
Seiten (von - bis)	3123-3128
Seitenumfang	6
ISSN	0020-1693
DOIs	https://doi.org/10.1016/j.ica.2006.01.011
Publikationsstatus	Veröffentlicht - 01.07.2006

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@article{b49bf3aceae44689bdc9aba3e33b80fc,

title = "X-ray and57Fe M{\"o}ssbauer study on a Fe(III) complex of 2-acetyl-1,3-indandione",

abstract = "Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed M{\"o}ssbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin-spin magnetic relaxation process. Two different approaches for computer processing of the experimental M{\"o}ssbauer spectra are considered. {\textcopyright} 2006 Elsevier B.V. All rights reserved.",

author = "Anife Ahmedova and Ventzislav Rusanov and Alan Hazell and Wolny, \{Juliusz A.\} and Georgi Gochev and Trautwein, \{Alfred X.\} and Mariana Mitewa",

year = "2006",

month = jul,

day = "1",

doi = "10.1016/j.ica.2006.01.011",

language = "English",

volume = "359",

pages = "3123--3128",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - X-ray and57Fe Mössbauer study on a Fe(III) complex of 2-acetyl-1,3-indandione

AU - Ahmedova, Anife

AU - Rusanov, Ventzislav

AU - Hazell, Alan

AU - Wolny, Juliusz A.

AU - Gochev, Georgi

AU - Trautwein, Alfred X.

AU - Mitewa, Mariana

PY - 2006/7/1

Y1 - 2006/7/1

N2 - Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed Mössbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin-spin magnetic relaxation process. Two different approaches for computer processing of the experimental Mössbauer spectra are considered. © 2006 Elsevier B.V. All rights reserved.

AB - Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed Mössbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin-spin magnetic relaxation process. Two different approaches for computer processing of the experimental Mössbauer spectra are considered. © 2006 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.ica.2006.01.011

DO - 10.1016/j.ica.2006.01.011

M3 - Journal articles

SN - 0020-1693

VL - 359

SP - 3123

EP - 3128

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 10

ER -

X-ray and57Fe Mössbauer study on a Fe(III) complex of 2-acetyl-1,3-indandione

Abstract

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