Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations

Rolf W. Saalfrank; Roman Burak; Alexandra Breit; Dietmar Stalke; Regine Herbst‐Irmer; Jörg Daub; Michael Porsch; Eckhard Bill; Markus Müther; Alfred X. Trautwein

doi:10.1002/anie.199416211

Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations

Rolf W. Saalfrank^*, Roman Burak, Alexandra Breit, Dietmar Stalke, Regine Herbst‐Irmer, Jörg Daub, Michael Porsch, Eckhard Bill, Markus Müther, Alfred X. Trautwein

^*Korrespondierende/r Autor/-in für diese Arbeit

Institut für Physik

143 Zitate (Scopus)

Abstract

In a simple one‐pot reaction the host‐guest compounds 1 (white spheres Fe^III; black = Fe^II; gray = NH 4+; angled rods = 2: R = Me, Et) are accessible in gram quantities by self‐assembly. They are the only fully characterized redox isomers whose cyclic voltammograms display four quasi‐reversible waves and whose mixed‐valent character has been established by Mössbauer spectra. The endohedral complexation of one NH 4+ ion in 1 has been confirmed by X‐ray crystallography. (Figure Presented.)

Originalsprache	Englisch
Zeitschrift	Angewandte Chemie International Edition in English
Jahrgang	33
Ausgabenummer	15-16
Seiten (von - bis)	1621-1623
Seitenumfang	3
ISSN	0570-0833
DOIs	https://doi.org/10.1002/anie.199416211
Publikationsstatus	Veröffentlicht - 02.09.1994

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Saalfrank, R. W., Burak, R., Breit, A., Stalke, D., Herbst‐Irmer, R., Daub, J., Porsch, M., Bill, E., Müther, M., & Trautwein, A. X. (1994). Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations. Angewandte Chemie International Edition in English, 33(15-16), 1621-1623. https://doi.org/10.1002/anie.199416211

@article{2a961e62661b4412abce2fd59f585705,

title = "Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations",

abstract = "In a simple one‐pot reaction the host‐guest compounds 1 (white spheres FeIII; black = FeII; gray = NH 4+; angled rods = 2: R = Me, Et) are accessible in gram quantities by self‐assembly. They are the only fully characterized redox isomers whose cyclic voltammograms display four quasi‐reversible waves and whose mixed‐valent character has been established by M{\"o}ssbauer spectra. The endohedral complexation of one NH 4+ ion in 1 has been confirmed by X‐ray crystallography. (Figure Presented.)",

author = "Saalfrank, \{Rolf W.\} and Roman Burak and Alexandra Breit and Dietmar Stalke and Regine Herbst‐Irmer and J{\"o}rg Daub and Michael Porsch and Eckhard Bill and Markus M{\"u}ther and Trautwein, \{Alfred X.\}",

year = "1994",

month = sep,

day = "2",

doi = "10.1002/anie.199416211",

language = "English",

volume = "33",

pages = "1621--1623",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

number = "15-16",

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Saalfrank, RW, Burak, R, Breit, A, Stalke, D, Herbst‐Irmer, R, Daub, J, Porsch, M, Bill, E, Müther, M & Trautwein, AX 1994, 'Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations', Angewandte Chemie International Edition in English, Jg. 33, Nr. 15-16, S. 1621-1623. https://doi.org/10.1002/anie.199416211

Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations. / Saalfrank, Rolf W.; Burak, Roman; Breit, Alexandra et al.
in: Angewandte Chemie International Edition in English, Jahrgang 33, Nr. 15-16, 02.09.1994, S. 1621-1623.

Publikation: Beiträge in Fachzeitschriften › Zeitschriftenaufsätze › Forschung › Begutachtung

TY - JOUR

T1 - Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations

AU - Saalfrank, Rolf W.

AU - Burak, Roman

AU - Breit, Alexandra

AU - Stalke, Dietmar

AU - Herbst‐Irmer, Regine

AU - Daub, Jörg

AU - Porsch, Michael

AU - Bill, Eckhard

AU - Müther, Markus

AU - Trautwein, Alfred X.

PY - 1994/9/2

Y1 - 1994/9/2

N2 - In a simple one‐pot reaction the host‐guest compounds 1 (white spheres FeIII; black = FeII; gray = NH 4+; angled rods = 2: R = Me, Et) are accessible in gram quantities by self‐assembly. They are the only fully characterized redox isomers whose cyclic voltammograms display four quasi‐reversible waves and whose mixed‐valent character has been established by Mössbauer spectra. The endohedral complexation of one NH 4+ ion in 1 has been confirmed by X‐ray crystallography. (Figure Presented.)

AB - In a simple one‐pot reaction the host‐guest compounds 1 (white spheres FeIII; black = FeII; gray = NH 4+; angled rods = 2: R = Me, Et) are accessible in gram quantities by self‐assembly. They are the only fully characterized redox isomers whose cyclic voltammograms display four quasi‐reversible waves and whose mixed‐valent character has been established by Mössbauer spectra. The endohedral complexation of one NH 4+ ion in 1 has been confirmed by X‐ray crystallography. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33748240270

U2 - 10.1002/anie.199416211

DO - 10.1002/anie.199416211

M3 - Journal articles

AN - SCOPUS:33748240270

SN - 0570-0833

VL - 33

SP - 1621

EP - 1623

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 15-16

ER -

Mixed‐Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations

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