TY - JOUR
T1 - Isolation of a spin-frustrated imidazolate-bridged trinuclear copper(II) complex potentially relevant to the multicopper oxidases
AU - Chaudhuri, Phalguni
AU - Karpenstein, Ina
AU - Winter, Manuela
AU - Butzlaff, Christian
AU - Bill, Eckhard
AU - Trautwein, Alfred X.
AU - Flörke, Ulrich
AU - Haupt, Hans Jürgen
PY - 1992/12/1
Y1 - 1992/12/1
N2 - The reaction of Cu(MeCO2)2·H2O with 1,4,7-trimethyl-1,4,7-triazacyclononane (L) and imidazole (ImH) in methanol affords, in the presence of a small amount of triethylamine and NaClO 4, the blue trinuclear complex [L3Cu3(Im) 3](ClO4)3 which has been characterized by X-ray crystallography, EPR and magnetic susceptibility measurements to be a spin-frustrated triangular imidazolate-bridged copper(II) complex without any μ3-X ligand.
AB - The reaction of Cu(MeCO2)2·H2O with 1,4,7-trimethyl-1,4,7-triazacyclononane (L) and imidazole (ImH) in methanol affords, in the presence of a small amount of triethylamine and NaClO 4, the blue trinuclear complex [L3Cu3(Im) 3](ClO4)3 which has been characterized by X-ray crystallography, EPR and magnetic susceptibility measurements to be a spin-frustrated triangular imidazolate-bridged copper(II) complex without any μ3-X ligand.
UR - http://www.scopus.com/inward/record.url?scp=37049075107&partnerID=8YFLogxK
U2 - 10.1039/C39920000321
DO - 10.1039/C39920000321
M3 - Journal articles
AN - SCOPUS:37049075107
SN - 0022-4936
SP - 321
EP - 322
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 4
ER -
