High-spin low-spin transition

H. Grünsteudel; H. Paulsen; H. Winkler; A. X. Trautwein; H. Toftlund

doi:10.1023/A:1017056831002

High-spin low-spin transition

H. Grünsteudel, H. Paulsen, H. Winkler, A. X. Trautwein^*, H. Toftlund

^*Korrespondierende/r Autor/-in für diese Arbeit

Institut für Physik

University of Southern Denmark

7 Zitate (Scopus)

Abstract

Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)₂] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.

Originalsprache	Englisch
Zeitschrift	Hyperfine Interactions
Jahrgang	123-124
Ausgabenummer	1-4
Seiten (von - bis)	841-846
Seitenumfang	6
ISSN	0304-3843
DOIs	https://doi.org/10.1023/A:1017056831002
Publikationsstatus	Veröffentlicht - 01.12.1999

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10.1023/A:1017056831002

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abstract = "Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)2] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.",

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AU - Grünsteudel, H.

AU - Paulsen, H.

AU - Winkler, H.

AU - Trautwein, A. X.

AU - Toftlund, H.

PY - 1999/12/1

Y1 - 1999/12/1

N2 - Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)2] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.

AB - Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS)2] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron-ligand bond stretching upon spin crossover has unambiguously been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.

UR - https://www.scopus.com/pages/publications/0043046074

U2 - 10.1023/A:1017056831002

DO - 10.1023/A:1017056831002

M3 - Journal articles

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VL - 123-124

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JO - Hyperfine Interactions

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High-spin low-spin transition

Abstract

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