Formation and characterization of very small iron clusters in zeolites

H. M. Ziethen; G. Doppler; A. X. Trautwein

doi:10.1007/BF02395585

Formation and characterization of very small iron clusters in zeolites

H. M. Ziethen^*, G. Doppler, A. X. Trautwein

^*Korrespondierende/r Autor/-in für diese Arbeit

Institut für Physik

5 Zitate (Scopus)

Abstract

We have investigated the thermal decomposition of Fe(CO)₅ in zeolite of Faujasite-type X and we have used mass spectroscopy and Mössbauer spectroscopy to monitor the formation of decomposition products. We have concluded from our studies that the pathway for the formation of crystalline iron clusters considerable depends on vacuum and heat treatment of Fe(CO)₅ in NaX and includes as precursors mononuclear and polynuclear Fe(CO)₃-systems and non-crystalline iron clusters.

Originalsprache	Englisch
Zeitschrift	Hyperfine Interactions
Jahrgang	42
Ausgabenummer	1-4
Seiten (von - bis)	1109-1112
Seitenumfang	4
ISSN	0304-3843
DOIs	https://doi.org/10.1007/BF02395585
Publikationsstatus	Veröffentlicht - 01.02.1988

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abstract = "We have investigated the thermal decomposition of Fe(CO)5 in zeolite of Faujasite-type X and we have used mass spectroscopy and M{\"o}ssbauer spectroscopy to monitor the formation of decomposition products. We have concluded from our studies that the pathway for the formation of crystalline iron clusters considerable depends on vacuum and heat treatment of Fe(CO)5 in NaX and includes as precursors mononuclear and polynuclear Fe(CO)3-systems and non-crystalline iron clusters.",

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AU - Ziethen, H. M.

AU - Doppler, G.

AU - Trautwein, A. X.

PY - 1988/2/1

Y1 - 1988/2/1

N2 - We have investigated the thermal decomposition of Fe(CO)5 in zeolite of Faujasite-type X and we have used mass spectroscopy and Mössbauer spectroscopy to monitor the formation of decomposition products. We have concluded from our studies that the pathway for the formation of crystalline iron clusters considerable depends on vacuum and heat treatment of Fe(CO)5 in NaX and includes as precursors mononuclear and polynuclear Fe(CO)3-systems and non-crystalline iron clusters.

AB - We have investigated the thermal decomposition of Fe(CO)5 in zeolite of Faujasite-type X and we have used mass spectroscopy and Mössbauer spectroscopy to monitor the formation of decomposition products. We have concluded from our studies that the pathway for the formation of crystalline iron clusters considerable depends on vacuum and heat treatment of Fe(CO)5 in NaX and includes as precursors mononuclear and polynuclear Fe(CO)3-systems and non-crystalline iron clusters.

UR - https://www.scopus.com/pages/publications/34250097682

U2 - 10.1007/BF02395585

DO - 10.1007/BF02395585

M3 - Journal articles

AN - SCOPUS:34250097682

SN - 0304-3843

VL - 42

SP - 1109

EP - 1112

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1-4

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Formation and characterization of very small iron clusters in zeolites

Abstract

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