Fe57 Mössbauer spectroscopic studies of iron silicates with the mordenite topology

A. J. Chandwadkar*, S. K. Date, E. Bill, A. Trautwein

*Korrespondierende/r Autor/-in für diese Arbeit
10 Zitate (Scopus)

Abstract

Fe57 Mössbauer spectroscopic studies on an as-synthesized sample of iron silicates with the mordenite topology/mordenite (Fe)/ferrimordenite, which was substantially free from Al ( SiO2 Al2O3 > 1000), have been carried out at room temperature (RT). 4.2 K, and in the presence of an externally applied magnetic field 4.13 T). The derived hyperfine interaction parameters at RT (IS = 0.24 ± 0.02 mm/s, Δ EQ = 0.59 ± 0.02 mm/s, and at 4.2 K, IS = 0.34 ± 0.02 mm/s, Δ EQ = 0.61 ± 0.02 mm/s), clearly indicated the presence of most of the iron ions at high-spin Fe3+ (6S 5 2) in nearly symmetric tetrahedral sites. Low-temperature/high-magnetic field spectra revealed the average internal field of 460 ± 10 KOe. These results confirm the uniform dispersion of Fe3+ ions in the tetrahedral framework of ferrimordenite.

OriginalspracheEnglisch
ZeitschriftZeolites
Jahrgang12
Ausgabenummer2
Seiten (von - bis)180-182
Seitenumfang3
ISSN0144-2449
DOIs
PublikationsstatusVeröffentlicht - 01.02.1992

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